Addition of magnesium oxide to zirconia toughened alumina
The present application is directed to a zirconia toughened alumina body and process for making the body. The process involves combining tetragonally stabilized ZrO 2 nanoparticles, Mg(OH) 2 particles and alumina powder into a mixture. All particles of the mixture are milled, formed into a green compact and then sintered. The final composition of the body includes α-Al 2 O 3 toughened with 0.5 to 2.5 weight percent ZrO 2 in a stabilized tetragonal form and 0.03 to 0.10 weight percent MgO. The composition results in an Al 2 O 3 body with a density less than 4.0 g/cc and strength greater than 50 kpsi.
1. A ceramic, comprising:
a) 0.5 to 2.5 weight percent ZrO 2 in the form of crystalline grains and stabilized in a substantially tetragonal crystal structure;
b) 0.03 to 0.10 weight percent MgO in the form of crystalline grains; and
c) the remainder of the ceramic being substantially α-Al 2 O 3 .
2. A ceramic as recited in claim 1 , wherein said weight percent ZrO 2 is from 1.0 to 2.0.
3. A ceramic as recited in claim 1 , wherein said weight percent MgO is from 0.03 to 0.05.
4. A ceramic as recited in claim 1 , wherein said ceramic has an actual density of less than 4.0 g/cc.
5. A ceramic as recited in claim 1 , wherein said α-Al 2 O 3 is in the form of crystalline grains having a diameter less than 6-microns.
6. A ceramic as recited in claim 1 , wherein the ceramic has strength greater than 50 kpsi.
7. A ceramic as recited in claim 1 , wherein the ceramic has strength greater than 55 kpsi.
8. A ceramic as recited in claim 1 , wherein said ZrO 2 is stabilized with Y 2 O 3 to from YZTP, wherein said YTZP is in the form of crystalline grains having a diameter of less than 0.1-microns.
9. A ceramic as recited in claim 1 , wherein said tetragonal crystal structure of Zr0 2 is stabilized with a stabilizing agent that is at least one selected from the group consisting of Y 2 O 3 and CeO 2 .