Lithium manganese oxide positive active material for lithium ion secondary battery and lithium ion secondary battery including the same
Provided are a lithium manganese oxide positive active material for a lithium ion secondary battery and a lithium ion secondary battery including the same. The lithium manganese oxide positive active material includes a spinel lithium manganese oxide of three or more types of particles having different sizes mixed therein, wherein first type particles have an average diameter of 5 μm or greater, second type particles have an average diameter of 1 μm or less, third type particles have an average diameter of 200 nm or less, and the average diameter of the second type particles is greater than that of the third type particles.
1. A lithium manganese oxide positive active material for a lithium ion secondary battery, the positive active material comprising:
a spinel lithium manganese oxide of three or more types of particles having different sizes mixed therein, wherein
first spinel lithium manganese oxide particles have an average diameter of 5 μm or greater, second spinel lithium manganese oxide particles have an average diameter of 1 μm or less, third spinel lithium manganese oxide particles have an average diameter of 200 nm or less, the average diameter of the second spinel lithium manganese oxide particles is greater than that of the third spinel lithium manganese oxide particles,
a ratio of the number of second spinel lithium manganese oxide particles to the number of third spinel lithium manganese oxide particles is in a range between 1 and 4,
the first spinel lithium manganese oxide particles are shaped of spheres, and
the third spinel lithium manganese oxide particles are shaped of rods.
2. The lithium manganese oxide positive active material of claim 1 , wherein a ratio of the number of first spinel lithium manganese oxide particles to the number of second spinel lithium manganese oxide particles and a ratio of the number of second spinel lithium manganese oxide particles to the number of third spinel lithium manganese oxide particles are in a range between 1 and 4.
3. The lithium manganese oxide positive active material of claim 1 , further comprising fourth spinel lithium manganese oxide particles having an average diameter of 40 nm or less, wherein the average diameter of the third spinel lithium manganese oxide particles is greater than that of the fourth spinel lithium manganese oxide particles.
4. The lithium manganese oxide positive active material of claim 3 , wherein the fourth spinel lithium manganese oxide particles are shaped of nanowires.
5. The lithium manganese oxide positive active material of claim 1 , wherein the spinel lithium manganese oxide includes at least one selected from the group consisting of LiMn 2 O 4 , LiM x Mn 2-x O 4 , where M is at least one selected from the group consisting of Ni, Zr, Co, Mg, Mo, Al and Ag, and 0<x<1, and LiM x Mn 2-x O 4-z F z , where M is at least one selected from the group consisting of Ni, Zr, Co, Mg, Mo, Al and Ag, 0<x<1, and 0<z<1.
6. A lithium ion secondary battery comprising a positive electrode including the positive active material of claim 1 , a negative electrode and an electrolyte.
7. A lithium ion secondary battery comprising a positive electrode including the positive active material of claim 2 , a negative electrode and an electrolyte.
8. A lithium ion secondary battery comprising a positive electrode including the positive active material of claim 3 , a negative electrode and an electrolyte.
9. A lithium ion secondary battery comprising a positive electrode including the positive active material of claim 4 , a negative electrode and an electrolyte.
10. A lithium ion secondary battery comprising a positive electrode including the positive active material of claim 5 , a negative electrode and an electrolyte.