Silane moisture curable hot melts
View Patent ↗The present invention relates to moisture-curable silane-reactive hot melt compositions having an acrylate-urethane copolymer moiety. Desirably, the silane groups contain alkoxy functionality to enable and enhance moisture curing. Such compositions provide enhanced green strength without sacrificing other desirable properties.
1. A hot melt composition having terminal moisture-curable silane groups formed by combining the components of a composition comprising:
a.) at least one polyacrylate containing active hydrogen groups randomly distributed along the polyacrylate chain;
b.) at least one polyol;
c.) at least one polyisocyanate;
d.) at least one moisture-curable end-capping isocyanato silane.
2. The composition of claim 1 , wherein the active hydrogen groups on said polyacrylate are present as hydroxyl groups having a hydroxyl number of 0.5 to 18.
3. The composition of claim 1 , wherein the at least one moisture-curable endcapping isocyanatosilane includes alkoxy groups.
4. The composition of claim 1 , wherein the at least one polyacrylate has a number average molecular weight of about 3,000 to about 80,000 and a Tg of about 15° to about 85° C.
5. The composition of claim 1 , wherein the at least one polyol is a polyether polyols, polyester polyol or combination thereof.
6. The composition of claim 1 , wherein the at least one polyol comprises a polyether polyol having a number average molecular weight less than 4,000.
7. The composition of claim 1 , wherein the at least one polyol comprises a polyether polyol that is present in amounts of about 10% to 70% by weight of the total composition.
8. The composition of claim 1 , wherein the at least one polyacrylate is present in amounts of about 5% to about 50% by weight of the total composition.
9. The composition of claim 1 , further including at least one additional moisture curable silane blended therewith.
10. A process for making moisture curing silane-reactive hot melt composition comprising:
(i) forming an acrylate-urethane copolymer by reacting a composition comprising:
a.) at least one polyacrylate containing active hydrogen groups randomly distributed along the polyacrylate chain;
b.) at least one polyol;
c.) at least one polyisocyanate wherein the molar ratio of (a+b)/c is >1.0;
(ii) reacting the reaction product of (i) with a moisture curable isocyanotosilane.
11. The process of claim 10 , further including the step of waiting until the concentration of free isocyanate is essentially zero before adding the isocyanatosilane.
12. The composition of claim 10 , wherein the active hydrogen groups on said at least one polyacrylate are present as hydroxyl groups having a hydroxyl number of 0.5 to 18.
13. The process of claim 10 , further comprising adding at least one additive selected from the group consisting of moisture cure catalysts, adhesion promoters, tackifiers, plasticizers, fillers, pigments, stabilizers, flame retardants, conductive agents, rheology modifiers, moisture scavengers, antioxidants, UV barriers, waxes, oligomeric polymer resins, thermoplastic polymer resins, moisture curable resins, and combinations thereof.
14. A method of forming a coating on a substrate comprising applying the composition of claim 1 to a substrate and permitting it to cure.
15. An article comprising cured reaction products of the moisture-curing silane-reactive functionalized hot melt composition of claim 1 .
16. The composition of claim 1 , wherein the terminal moisture-curable silane group comprises an alkoxy moiety.