Synthesis of polyoxometalate-loaded epoxy composites
The synthesis of a polyoxometalate-loaded epoxy uses a one-step cure by applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin. Such polyoxometalate-loaded epoxy composites afford the cured epoxy unique properties imparted by the intrinsic properties of the polyoxometalate. For example, polyoxometalate-loaded epoxy composites can be used as corrosion resistant epoxy coatings, for encapsulation of electronics with improved dielectric properties, and for structural applications with improved mechanical properties.
1. A method of synthesis of polyoxometalate-loaded epoxy, comprising:
adding a polyoxometalate to an epoxy resin, wherein the polyoxometalate comprises a heteropolyacid having a Dawson structure having a chemical formula [H n X 2 M 18 O 62 ], wherein X is a 4A-5A element and M is a IVB-VIB transition metal; and
applying an external stimulus to release the acid from the polyoxometalate and thereby catalyze the cure reaction of the epoxy resin.
2. The method of claim 1 , wherein M is V, Nb, Mo, or W.
3. The method of claim 1 , wherein X is P or Si.
4. The method of claim 1 , wherein the polyoxometalate is complexed with an organic base.
5. The method of claim 1 , wherein the epoxy resin has a pK a greater than 7.
6. The method of claim 5 , wherein the epoxy resin comprises N,N-diglycidyl-4-glycidyloxyaniline resin.
7. The method of claim 1 , wherein the external stimulus comprises a photo or thermal stimulus.