Catalytic composition for production of olefins with decreased oxygenate byproducts
Catalytic composition for production of olefins and methods of using same to decrease production of oxygenate byproducts. The catalytic composition includes an admixture of an alumina dehydration catalyst and at least one additional metal oxide.
1. An improved method for producing olefins by alkanol dehydration, wherein the improved method comprises decreasing acetaldehyde byproduct by using a catalytic composition consisting of an admixture of an alumina dehydration catalyst and yttrium oxide present in an amount within a range of from 5 percent by weight to 50 percent by weight based upon a total catalytic composition weight, wherein the alkanol is ethanol, whereby the acetaldehyde byproduct is decreased relative to the same olefins produced from the same alkanol at the same temperature although using the same alumina dehydration catalyst in an absence of the yttrium oxide.
2. The improved method of claim 1 , further comprising the production of the olefins having a decreased acetaldehyde byproduct relative to the same olefins produced from the same alkanol at the same temperature although using a dehydration catalyst consisting of an amorphous aluminosilicate or an aluminum-containing molecular sieve in combination with the yttrium oxide.
3. The improved method of claim 1 , further comprising increasing production of propylene relative to the propylene produced with the alumina dehydration catalyst in an absence of the yttrium oxide.
4. The improved method of claim 1 , further comprising positioning the catalytic composition in a single reaction zone of a fixed bed continuous flow reactor.
5. The improved method of claim 1 , wherein the catalytic composition comprises gamma-alumina.
6. A method for selective reduction of acetaldehyde byproduct formed during production of an olefin by alkanol dehydration, the method comprising contacting a feed, wherein the feed comprises ethanol, with a catalytic composition consisting of an admixture of an alumina dehydration catalyst and yttrium oxide present in an amount within a range of from 5 percent by weight to 50 percent by weight based upon a total catalytic composition weight to provide an olefin total yield and an acetaldehyde byproduct yield,wherein the acetaldehyde byproduct yield is decreased relative to a corresponding acetaldehyde byproduct yield formed during production of the same olefin produced from the same alkanol at the same temperature although using the same alumina dehydration catalyst in absence of the yttrium oxide.
7. The method of claim 6 , wherein the acetaldehyde yield is reduced to essentially zero.
8. The method of claim 6 , wherein the catalytic composition comprises gamma-alumina.