Use of polyamide for the preparation of injection-molded articles and resulting articles
The use of thermoplastic polymers for the preparation of injection-molded articles and the resulting articles are described. Also described, is the use of a lubricated polyamide, obtained by means of the addition of at least one lubricant during the polyamide polymerization method, for the preparation of injection-molded articles.
1. A method of preparing an article, the method comprising:
manufacturing a polyamide by a polymerization process comprising a phase of distillation under pressure, a decompression phase, a finishing phase comprising a finisher, and a granulation phase;
wherein the polyamide is a polyamide of 6 or 66 type and exhibits a viscosity index, measured according to the standard ISO307, of from 95 ml/g to 125 ml/g;
introducing a lubricant, and optionally a chain-limiting agent, during the process for the polymerization of the polyamide, in the following way:
if the chain-limiting agent is introduced during the process for the polymerization of the polyamide, then said chain-limiting agent is introduced before the end of the finishing stage, and
the lubricant is introduced after the phase of distillation under pressure and before the end of the finisher; and
injection molding the article using the lubricated polyamide.
2. The method as defined in claim 1 , wherein the polyamide exhibits a viscosity index, measured according to the standard ISO307, of from 105 ml/g to 125 ml/g.
3. The method as defined in claim 2 , wherein the polyamide exhibits a viscosity index of from 110 ml/g to 122 ml/g.
4. The method as defined in claim 1 , wherein the lubricant is a paraffin, the mean number of carbon atoms of which is from 8 to 100.
5. The method as defined in claim 4 , wherein the mean number of carbons is from 12 to 80.
6. The method as defined in claim 4 , wherein the mean number of carbons is from 15 to 50.
7. The method as defined in claim 1 , wherein the lubricant is selected from the group consisting of a fatty acid, a fatty acid metal salt, a fatty acid ester, a fatty acid amide and a mixture thereof.
8. The method as defined in claim 7 , wherein the fatty acid is a stearic acid.
9. The method as defined in claim 7 , wherein the fatty acid metal salt is aluminum distearate.
10. The method as defined in claim 1 , wherein the lubricant is a mixture of paraffin and of fatty acid and/or of fatty acid metal salt.
11. The method as defined in claim 10 , wherein the lubricant is a mixture of paraffin, of a fatty acid and of a fatty acid metal salt.
12. The method as defined in claim 1 , wherein the lubricant represents from 0.1% by weight to 5% by weight, with respect to the weight of polyamide.
13. The method as defined in claim 1 , wherein the polyamide is obtained by a process comprising a phase of concentrating the N salt or a stage of mixing the monomers with water, a phase of distillation under pressure and a decompression phase, and in that the lubricant is introduced after the stage of distillation under pressure and before the end of the finisher.
14. The method as defined in claim 13 , wherein the lubricant is introduced after the decompression stage.
15. The method as defined in claim 13 , wherein the lubricant is introduced between the beginning and the end of the finisher.
16. The method as defined in claim 13 , wherein a chain-limiting agent is added during the process for the polymerization of the polyamide.
17. The method as defined in claim 16 , wherein the chain-limiting agent is selected from the group consisting of acetic acid, benzoic acid, lauric acid, propionic acid, benzylamine, n-hexadecylamine, n-octadecylamine and n-dodecylamine, and 4-amino-2,2,6,6-tetramethylpiperidine.
18. The method as defined in claim 16 , wherein the chain-limiting agent is introduced before or during the phase of concentrating the N salt or during the stage of mixing the monomers with water.
19. The method as defined in claim 1 , wherein the chain-limiting agent is selected from the group consisting of:
a monocarboxylic acid,
a dicarboxylic acid,
a metal salt of a monocarboxylic acid,
a metal salt of a dicarboxylic acid,
a monoamine,
a diamines, one of the functional groups of which is hindered, and
a mixture thereof.
20. The method as defined in claim 1 , wherein the polyamide, when the lubricant is introduced, is not subjected to a remelting stage.
21. The method as defined in claim 1 , wherein the lubricant is introduced through an inlet of the finisher.
22. The method as defined in claim 1 , wherein the lubricant is a liquid at ambient temperature.
23. The method as defined in claim 1 , wherein the lubricant and the chain-limiting agent are combined to form a mixture and the mixture is introduced after the phase of distillation under pressure and before the end of the finisher.