Aluminum alloy material for storage container for high-pressure hydrogen gas
View Patent ↗An object of the present invention is to provide a 6000-series aluminum alloy material for a high-pressure gas container which has both of resistance to hydrogen embrittlement and mechanical properties. In the aluminum alloy material for a high-pressure gas container, the contents of Fe, Mn and Cu fall within narrower ranges than the standard composition of AA6066 alloy. The aluminum alloy material is produced to have a structure in which a predetermined amount of fine dispersed particles are dispersed therein and coarse crystallized materials are small, and therefore strength and resistance to hydrogen embrittlement are improved, which are required for a high-pressure gas container.
1. An aluminum alloy material comprising, in mass %,
0.8 to 1.4% of Mg;
0.9 to 1.8% of Si;
less than 0.44% but more than 0% of Fe;
0.7 to 1.2% of Cu;
0.7 to 0.9% of Mn;
0 to 0.40% of Cr;
0 to 0.25% of Zn; and
0 to 0.20% of Ti;
with a remaining portion comprising Al and unavoidable impurities,
wherein a relationship between C and D satisfies the formula: D+0.0011×C−9.5≦0 when D represents an average density, in particles/μm 2 , of dispersed particles each having an equivalent circle diameter of 800 nm or less and C represents an average density, in particles/mm 2 , of crystallized materials each having an equivalent circle diameter of 0.38 μm or more in a structure of the aluminum alloy material, and
wherein the aluminum alloy material is suitable for a storage container for high pressure hydrogen gas.
2. The aluminum alloy material of claim 1 ,
wherein after being subjected to a T6 tempering treatment, the aluminum alloy material has mechanical properties of
a tensile strength of 410 MPa or more,
a 0.2% yield strength of 360 MPa or more and
an elongation of 10% or more, and
the aluminum alloy material is suitable for use as a liner material for a storage container for high-pressure hydrogen gas in such a manner that a fiber-reinforced resin or a fiber for reinforcement is wound around the outside of the aluminum alloy material.
3. The aluminum alloy material of claim 1 ,
wherein the aluminum alloy material has an index of a resistance to hydrogen embrittlement represented by [(δ1-δ2)/δ1] of 0.1 or less, including a negative value, when δ1 represents an elongation value of the aluminum alloy material that is tensile-deformed in a dried atmosphere of 5% RH or less and δ2 represents an elongation value of the aluminum alloy material that is tensile-deformed in a highly humid atmosphere of 90% RH or more in the case where the aluminum alloy material is tensile-deformed at a strain rate of 6.7×10 −7 s −1 or less under different atmospheric conditions.
4. The aluminum alloy material of claim 3 , wherein the index of a resistance to hydrogen embrittlement is 0.05 or less.
5. The aluminum alloy material of claim 1 , comprising 0.04 to less than 0.44% of Fe.
6. The aluminum alloy material of claim 1 , comprising 0.04 to 0.21% of Fe.
7. The aluminum alloy material of claim 1 , comprising 1.02 to 1.03% of Cu.
8. The aluminum alloy material of claim 1 , comprising 0.70 to 0.79% of Mn.
9. The aluminum alloy material of claim 1 , comprising 1.17 to 1.21% of Mg.
10. The aluminum alloy material of claim 2 , having a tensile strength of more than 425 MPa.
11. The aluminum alloy material of claim 2 , having a 0.2% yield strength of 375 MPa or more.
12. The aluminum alloy material of claim 2 , having an elongation of 12% or more.
13. The aluminum alloy material of claim 1 , wherein C is 2150 to 3025.
14. The aluminum alloy material of claim 1 , wherein D is 1.3 to 1.4.
15. The aluminum alloy material of claim 1 , comprising more than 0% of Cr.
16. The aluminum alloy material of claim 1 , comprising more than 0% of Zn.
17. The aluminum alloy material of claim 1 , comprising more than 0% of Ti.
18. The aluminum alloy material of claim 1 , comprising more than 0% of Cr, more than 0% of Zn, and more than 0% of Ti.
19. The aluminum alloy material of claim 1 , comprising 0.015 to 0.018% of Cr.
20. The aluminum alloy material of claim 1 , comprising 0.017 to 0.024% of Ti.