Positive electrode active material for lithium-ion battery and lithium-ion battery
Provided is a lithium ion battery wherein the content of an iron element contained in a positive electrode active material (measured with an ICP emission spectrophotometer) is 10 ppm or more, and magnetic materials having a size of 0.70 times or greater than the thickness of a separator layer are substantially not included in order to provide a lithium ion battery which has small voltage drop during a charge state or under storage at high temperatures.
1. A lithium ion battery comprising positive electrode active material and a separator layer, wherein the content of iron contained in the positive electrode active material, when measured with an ICP emission spectrophotometer, is 10 ppm or more;
the content of the magnetic materials having a size of 0.70 times or greater than the thickness of a separator layer is zero when measured according to the following measurement method:
the maximum particle diameter (Dmax) of the positive electrode active material is 0.70 times or greater than the thickness of a separator layer,
the positive electrode active material is subjected to size classification to separate the positive electrode active material having a size of 0.70 times or greater than the thickness of a separator layer, and the separated positive electrode active material, ion exchange water, and a cylindrical stirring bar-type magnet coated with tetrafluoroethylene are added into a resinous container, which is then placed on a ball mill rotating stage and rotated to produce a slurry; the magnet is taken out, immersed in ion exchange water, and washed with an ultrasonic cleaning apparatus to remove excess powder attached to the magnet; the magnet is taken out, immersed in aqua regia, and heated in the aqua regia at 80° C. for 30 minutes to dissolve the magnetic materials; the aqua regia containing the magnetic materials dissolved therein is analyzed for the amounts of iron, chromium and zinc with an ICP emission spectrophotometer, and, with the total amounts thereof as the amount of magnetic materials, the amount of magnetic materials per weight of the positive electrode active material is calculated.
2. The lithium ion battery according to claim 1 , wherein the positive electrode active material is spinel type lithium transition metal oxides, lithium transition metal oxides with layer structure, or olivine, or a mixture of two or more thereof.