Damage tolerant aluminium material having a layered microstructure
A wrought aluminium material with improved damage tolerance while preserving the high strength of the material is disclosed. Furthermore, a cast aluminium material of a precipitation hardenable aluminium alloy is disclosed, the material comprising grains having two distinct zones with a first centre zone enriched in elements capable of reacting peritectically with aluminium and a second zone, surrounding the first zone, enriched in elements capable of reacting eutectically with aluminium.
1. A method of producing a wrought aluminium material, comprising the steps:
producing a cast aluminium material of a precipitation hardenable aluminium alloy, wherein the precipitation hardenable aluminium alloy consists of, in wt %:
0.3-1.5 Si,
0.3-1.5 Mg,
≤0.3 Mn,
<0.5 Cu,
<0.5 Fe,
<0.3 Nb,
<0.3 V,
<0.3 Cr,
<0.2 Zn,
<0.2 Ti,
<0.2 Mo,
<0.2 Zr, and
unavoidable impurities each 0.05 wt. % maximum and the total of impurities 0.15 wt. % maximum, and
balance aluminium,
wherein the cast material further comprises grains, dendrites or cells having a two-zone cast structure with two distinct zones including a first centre zone enriched in elements capable of reacting peritectically with aluminium and a second zone, surrounding the first zone, enriched in elements capable of reacting eutectically with aluminium, the first zone occupying 20-50% of the total volume measured on the cross section as peritectic hills in the interference contrast in LOM,
wherein the precipitation hardenable aluminium alloy comprises peritectic alloying elements with a combined partition coefficient Σk of above 3 and a proportion of peritectic elements of more than 0.02×[wt % eutectic alloying elements] able to suppress the local eutectic element content in the peritectic zone to <0.8×[the average eutectic alloying elements content of the alloy in wt %], and
wherein the precipitation hardenable aluminium alloy is cast while controlling the casting speed so as to produce the two-zone cast structure, wherein the solidification time during casting is controlled to at least 75 seconds;
optionally homogenising the cast material with the two-zone cast structure at homogenization conditions that preserve the two distinct zones of the cast material;
optionally preheating the billet;
deforming the cast structure to produce a material with a layered structure comprising alternate layers of different mechanical properties;
cooling said material; and
optionally heat treating said material.
2. The method according to claim 1 , where the material is deformed by extrusion or forging.
3. The method according to claim 1 , wherein the combined partition coefficient Σk is above 5.
4. The method according to claim 3 , wherein the combined partition coefficient Σk is above 8.
5. The method according to claim 1 , wherein the Mg/Si ratio of the precipitation hardenable aluminium alloy is >1.
6. A method of producing a wrought aluminium material, comprising the steps:
producing a cast aluminium material of a precipitation hardenable aluminium alloy, wherein the precipitation hardenable aluminium alloy consists of, in wt %:
0.3-1.5 Si,
0.3-1.5 Mg,
≤0.3 Mn,
<0.5 Cu,
<0.5 Fe,
<0.3 Nb,
<0.3 V,
<0.3 Cr,
<0.2 Zn,
<0.2 Ti,
<0.2 Mo,
<0.2 Zr, and
unavoidable impurities each 0.05 wt. % maximum and the total of impurities 0.15 wt. % maximum, and
balance aluminium,
wherein the cast material further comprises grains, dendrites or cells having a two-zone cast structure with two distinct zones including a first centre zone enriched in elements capable of reacting peritectically with aluminium and a second zone, surrounding the first zone, enriched in elements capable of reacting eutectically with aluminium, the first zone occupying 20-50% of the total volume measured on the cross section as peritectic hills in the interference contrast in LOM,
wherein the precipitation hardenable aluminium alloy comprises peritectic alloying elements with a combined partition coefficient Σk of above 3 and a proportion of peritectic elements of more than 0.02×[wt % eutectic alloying elements] able to suppress the local eutectic element content in the peritectic zone to <0.8×[the average eutectic alloying elements content of the alloy in wt %], and
wherein the precipitation hardenable aluminium alloy is cast while controlling the casting speed so as to produce the two-zone cast structure, and wherein the solidification time during casting is controlled to at least 75 seconds;
optionally preheating the cast material comprising the two-zone cast structure;
deforming the cast material comprising the two-zone cast structure to produce a material with a layered structure comprising alternate layers of different mechanical properties;
cooling said material; and
optionally heat treating said material.