IP Library Granted Patent US 8,643,197
Granted Patent B1
US 8,643,197 · App. 13/651,995 · Granted Feb 4, 2014

Encapsulant for a semiconductor device

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Quick Facts
Patent No.
US 8,643,197
App. No.
13/651,995
Granted
Feb 4, 2014
Kind
B1
Abstract

A mold compound is provided for encapsulating a semiconductor device ( 101 ). The mold compound comprises at least approximately 70% by weight silica fillers, at least approximately 10% by weight epoxy resin system, and beneficial ions that are beneficial with respect to copper ball bond corrosion. A total level of the beneficial ions in the mold compound is at least approximately 100 ppm.

Claims (65)

1. A mold compound for encapsulating an electronic device, the mold compound comprising:

silica fillers;

epoxy resin system; and

beneficial ions that are beneficial with respect to copper ball bond corrosion,

wherein a total level of the beneficial ions in the mold compound is at least approximately 100 ppm, and wherein the beneficial ions are ions selected from the group consisting of formate (HCOO) − , acetate (CH 3 CO 2 ) − , phosphate (PO 4 ) 3− , silicate (SiO 4 ) 4− , nitrate (NO 3 ) − , nitrite (NO 2 ) − , and sulfate (SO 4 ) 2− .

2. The mold compound of claim 1 , wherein the beneficial ions are a combination of formate (HCOO) − and acetate (CH 3 CO 2 ) − ions.

3. The mold compound of claim 1 ,

wherein the mold compound comprises at least approximately 70% by weight silica fillers and at least approximately 10% by weight epoxy resin system, and

the total level of the beneficial ions in the mold compound is less than or equal to 2000 ppm.

4. The mold compound of claim 1 ,

wherein a pH level of the mold compound is greater than or equal to 6.5, and

a level of chloride ions in the mold compound is less than or equal to 20 ppm.

5. The mold compound of claim 1 ,

wherein a pH level of the mold compound is 6.0-8.0,

a level of chloride ions in the mold compound is less than or equal to 5 ppm, and

an operating voltage level of the electronic device is less than or equal to 65V.

6. The mold compound of claim 1 ,

wherein a pH level of the mold compound is greater than or equal to 5.0,

a level of chloride ions in the mold compound is less than or equal to 10 ppm, and

an operating voltage level of the electronic device is less than or equal to 6V.

7. The mold compound of claim 1 , wherein at least one of:

a moisture absorption level of the mold compound is less than 0.3% by weight,

an oxalate ion level of the mold compound is less than or equal to 50 ppm, and

a magnesium ion level of the mold compound is from 2 ppm to 200 ppm.

8. A mold compound for encapsulating an electronic device, a pH level of the mold compound being greater than or equal to 6.5, and a level of chloride ions in the mold compound being less than or equal to 20 ppm.

9. The mold compound of claim 8 ,

wherein the mold compound comprises at least approximately 70% by weight silica fillers, and at least approximately 10% by weight epoxy resin system, and

a pH level of the mold compound is from 6.5 to 7.5.

10. The mold compound of claim 8 ,

wherein a pH level of the mold compound is greater than or equal to 6.0,

a level of chloride ions in the mold compound is less than or equal to 5 ppm, and

an operating voltage level of the electronic device is less than or equal to 65V.

11. The mold compound of claim 8 ,

wherein a pH level of the mold compound is greater than or equal to 7.0,

a level of chloride ions in the mold compound is less than or equal to 10 ppm, and

an operating voltage level of the electronic device is less than or equal to 65V.

12. The mold compound of claim 8 ,

wherein a pH level of the mold compound is greater than or equal to 5.0,

a level of chloride ions in the mold compound is less than or equal to 10 ppm, and

an operating voltage level of the electronic device is less than or equal to 6V.

13. The mold compound of claim 8 , wherein an operating voltage level of the electronic device is less than or equal to 6V.

14. The mold compound of claim 8 , wherein at least one of:

a moisture absorption level of the mold compound is less than 0.3% by weight,

an oxalate ion level of the mold compound is less than or equal to 50 ppm, and

a magnesium ion level of the mold compound is from 2 ppm to 200 ppm.

15. A semiconductor device package comprising:

an electronic device that includes an aluminum bond pad;

a copper wire bonded to the aluminum bond pad; and

an encapsulant, the electronic device and the copper wire being encapsulated by the encapsulant,

wherein the encapsulant comprises:

epoxy resin system, and

beneficial ions that are beneficial with respect to copper ball bond corrosion, a total level of the beneficial ions in the encapsulant being at least approximately 20 ppm.

16. The semiconductor device package of claim 15 , wherein the beneficial ions are ions selected from the group consisting of formate, acetate, carbonate, phosphate, silicate, nitrate, nitrite, and sulfate.

17. The semiconductor device package of claim 15 ,

wherein the encapsulant comprises at least approximately 70% by weight silica fillers, and at least approximately 10% by weight epoxy resin system,

a pH level of the encapsulant is from 6.5 to 7.5, and

a level of chloride ions in the encapsulant is less than or equal to 20 ppm.

18. The semiconductor device package of claim 15 ,

wherein a pH level of the encapsulant is greater than or equal to 5.0,

a level of chloride ions in the encapsulant is less than or equal to 10 ppm, and

an operating voltage level of the electronic device is less than or equal to 6V.

19. The semiconductor device package of claim 15 , wherein at least one of:

a moisture absorption level of the encapsulant is less than 0.3% by weight,

an oxalate ion level of the encapsulant is less than or equal to 50 ppm, and

a magnesium ion level of the encapsulant is from 2 ppm to 200 ppm.

Assignments (16)
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040925 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Feb 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V. F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 052917/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE APPLICATION 11759915 AND REPLACE IT WITH APPLICATION 11759935 PREVIOUSLY RECORDED ON REEL 040928 FRAME 0001. ASSIGNOR(S) HEREBY CONFIRMS THE RELEASE OF SECURITY INTEREST. Recorded Jan 17, 2020
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 052915/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE TO CORRECT THE APPLICATION NO. FROM 13,883,290 TO 13,833,290 PREVIOUSLY RECORDED ON REEL 041703 FRAME 0536. ASSIGNOR(S) HEREBY CONFIRMS THE THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS.. Recorded Feb 20, 2019
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: SHENZHEN XINGUODU TECHNOLOGY CO., LTD.
Reel/Frame 048734/0001 →
CORRECTIVE ASSIGNMENT TO CORRECT THE REMOVE PATENTS 8108266 AND 8062324 AND REPLACE THEM WITH 6108266 AND 8060324 PREVIOUSLY RECORDED ON REEL 037518 FRAME 0292. ASSIGNOR(S) HEREBY CONFIRMS THE ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS. Recorded Feb 1, 2017
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 041703/0536 →
RELEASE OF SECURITY INTEREST Recorded Nov 7, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP B.V.
Reel/Frame 040928/0001 →
RELEASE OF SECURITY INTEREST Recorded Sep 21, 2016
From: MORGAN STANLEY SENIOR FUNDING, INC.
To: NXP, B.V., F/K/A FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 040925/0001 →
PATENT RELEASE Recorded Jan 14, 2016
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037494/0312 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 13, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037518/0292 →
ASSIGNMENT AND ASSUMPTION OF SECURITY INTEREST IN PATENTS Recorded Jan 12, 2016
From: CITIBANK, N.A.
To: MORGAN STANLEY SENIOR FUNDING, INC.
Reel/Frame 037486/0517 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0671 →
PATENT RELEASE Recorded Dec 21, 2015
From: CITIBANK, N.A., AS COLLATERAL AGENT
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 037357/0685 →
SECURITY AGREEMENT Recorded Nov 6, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 031591/0266 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Apr 22, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030258/0558 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Apr 22, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS NOTES COLLATERAL AGENT
Reel/Frame 030258/0523 →
SUPPLEMENT TO IP SECURITY AGREEMENT Recorded Apr 22, 2013
From: FREESCALE SEMICONDUCTOR, INC.
To: CITIBANK, N.A., AS COLLATERAL AGENT
Reel/Frame 030258/0540 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 15, 2012
From: CHOPIN, SHELIA F.; MATHEW, VARUGHESE; HIGGINS, LEO M., III; LEE, CHU-CHUNG
To: FREESCALE SEMICONDUCTOR, INC.
Reel/Frame 029130/0247 →