PFCB nanometer scale fibers
View Patent ↗A method for making a fibrous layer for fuel cell applications includes a step of combining a perfluorocyclobutyl-containing resin with a water soluble carrier resin to form a resinous mixture. The resinous mixture is then shaped to form a shaped resinous mixture. The shaped resinous mixture includes perfluorocyclobutyl-containing structures within the carrier resin. The shaped resinous mixture is contacted (i.e., washed) with water to separate the perfluorocyclobutyl-containing structures from the carrier resin. Optional protogenic groups and then a catalyst are added to the perfluorocyclobutyl-containing structures.
1. A method comprising:
combining a perfluorocyclobutyl-containing resin with a water soluble carrier resin to form a resinous mixture;
shaping the resinous mixture to form a shaped resinous mixture, the shaped resinous mixture having perfluorocyclobutyl-containing structures within the carrier resin;
contacting the shaped resinous mixture with water to separate the perfluorocyclobutyl-containing structures from the carrier resin;
optionally adding protogenic groups to the perfluorocyclobutyl-containing structures;
combining a catalyst with the perfluorocyclobutyl-containing structures to form an ink composition; and
applying the ink composition to a surface to form an anode catalyst layer or a cathode catalyst layer.
2. The method of claim 1 wherein the perfluorocyclobutyl-containing structures include a component selected from the group consisting of fibers, beads, spheres, and oblong shapes.
3. The method of claim 1 wherein the protogenic groups are SO 2 X, —PO 3 H 2 , or —COX where X is an —OH, a halogen, or an ester.
4. The method of claim 1 wherein the perfluorocyclobutyl-containing resin includes a plurality of electrically conductive particles.
5. The method of claim 4 wherein the electrically conductive particles are selected from the group consisting of carbon particles, graphite particles, metal particles, and combinations thereof.
6. The method of claim 1 wherein the carrier resin is a water-soluble polyamide.
7. The method of claim 1 wherein the carrier resin comprises poly(2-ethyl-2-oxazoline).
8. The method of claim 1 wherein the weight ratio of perfluorocyclobutyl-containing resin to carrier resin is from about 1:100 to about 10:1.
9. The method of claim 1 wherein the perfluorocyclobutyl-containing structures have an average diameter from about 5 nanometers to about 10 microns.
10. The method of claim 1 wherein the catalyst includes a component selected from the group consisting of gold, platinum, palladium, and combinations thereof.
11. A method comprising:
combining a perfluorocyclobutyl-containing resin with a water soluble carrier resin to form a resinous mixture;
extruding the resinous mixture to form an extruded resinous mixture, the extruded resinous mixture having perfluorocyclobutyl-containing fibers within the carrier resin;
contacting the extruded resinous mixture with water to separate the perfluorocyclobutyl-containing fibers from the carrier resin;
sulfonating the perfluorocyclobutyl-containing fibers;
coating at least a portion of the perfluorocyclobutyl-containing fibers with a catalyst;
combining the perfluorocyclobutyl-containing fibers with a solvent to form an ink composition; and
forming a fuel cell electrode layer from the ink composition.
12. The method of claim 11 wherein the perfluorocyclobutyl-containing resin includes a plurality of electrically conductive particles.
13. The method of claim 12 wherein the electrically conductive particles are selected from the group consisting of carbon particles, graphite particles, metal particles, and combinations thereof.
14. The method of claim 12 wherein the carrier resin is a water-soluble polyamide.
15. The method of claim 11 wherein the carrier resin comprises poly(2-ethyl-2-oxazoline).