Chemical transformation of lignocellulosic biomass into fuels and chemicals
A method for converting a carbohydrate to a furan in a polar aprotic solvent in the presence of a chloride, bromide, or iodide salt or a mixture thereof and optionally in the presence of an acid catalyst, a metal halide catalyst and/or an ionic liquid (up to 40 wt %). The method can be employed in particular to produce furfural or 5-hydroxymethylfurfural.
1. A method for converting a carbohydrate to a furan which comprises the steps of:
(a) preparing a mixture of the carbohydrate in a polar aprotic solvent containing a chromium halide; and
(b) heating the mixture to obtain a furan,
wherein the carbohydrate is a lignocellulosic feedstock and the polar aprotic solvent is an ionic liquid.
2. The method of claim 1 wherein the furan is 5-hydroxymethylfurfural or furfural.
3. The method of claim 1 wherein the ionic liquid is selected from an alkylimidazolium ionic liquid, an alkylimidazolium halide ionic liquid, an alkylimidazolium chloride ionic liquid, an alkylpyridinium ionic liquid, an alkylpyridinium halide ionic liquid, an alkylpyridinium chloride ionic liquid or a combination thereof.
4. The method of claim 3 wherein the ionic liquid is selected from [EMIM]CI, [BMIM]CI, [EMIM]Br, 1-ethyl-2,3-dimethylimidazolium chloride, 1-ethylpyridinium chloride, 1-butyl-4-methylpyridinium chloride, or a mixture thereof.
5. A method for making 2, 5-dimethylfuran which comprises the step of making 5-hydroxymethylfurfural by the method of claim 1 and thereafter converting 5-hydroxymethylfurfural to 2, 5-dimethylfuran.
6. A method for making furan which comprises the step of making furfural by the method of claim 1 and thereafter converting furfural to furan.
7. The method of claim 1 wherein the mixture further comprises acid.
8. The method of claim 7 wherein the acid is HCI.
9. The method of claim 1 wherein the chromium halide is a chromium chloride.
10. The method of claim 1 wherein the chromium halide is CrBr 3 .
11. The method of claim 1 wherein the lignocellulosic feedstock is corn stover.
12. The method of claim 1 wherein the mixture is heated to 80 to 140° C.
13. The method for making 2, 5-dimethylfuran of claim 5 wherein 5-hydroxymethylfurfural is converted to 2, 5-dimethylfuran by hydrogenolysis.
14. The method for making furan of claim 6 wherein furfural is converted to furan by decarbonylation.