Resin composition for refrigerant-transporting hose and method of producing the resin composition, and refrigerant-transporting hose
A resin composition for a refrigerant-transporting hose, including: a semi-aromatic polyamide resin (A) as a main component; an aliphatic polyamide resin (B); and an elastomer (C), in which the aliphatic polyamide resin (B) is dispersed in a phase formed of the semi-aromatic polyamide resin (A) and the elastomer (C), which is not crosslinked, is incorporated in the form of particles into the dispersed aliphatic polyamide resin (B). Thus, excellent refrigerant permeation resistance and acid resistance, and at the same time, for example, extrusion processability and flexibility, are obtained.
1. A refrigerant-transporting hose, comprising one or more constituent layers,
wherein at least an innermost layer of the constituent layers is formed of a resin composition containing a semi-aromatic polyamide resin (A) as a main component, an aliphatic polyamide resin (B) and an elastomer (C),
wherein the aliphatic polyamide resin (B) is dispersed in a phase formed of the semi-aromatic polyamide resin (A),
wherein the elastomer (C), which is not crosslinked, is incorporated in the form of particles into the dispersed aliphatic polyamide resin (B), and
wherein the semi-aromatic polyamide resin (A) is a polyamide 9T (PA9T).
2. A refrigerant-transporting hose according to claim 1 ,
wherein the layer formed of the resin composition is an inner layer of the hose, and the hose further comprises a rubber layer as an outer layer.
3. A refrigerant-transporting hose according to claim 1 ,
wherein the layer formed of the resin composition is an inner layer, and the hose further comprises a layer formed of an ethylene-propylene-diene rubber as an outer layer.
4. A method of producing a refrigerant-transporting hose according to claim 1 , the method comprising:
kneading an aliphatic polyamide resin (B) and an elastomer (C) that is not crosslinked to finely disperse the elastomer (C) in the aliphatic polyamide resin (B);
after the kneading, mixing the kneaded product and a semi-aromatic polyamide resin (A) so as to provide a resin composition for a refrigerant-transporting hose; and
melt-extruding the resin composition into a hose shape to form a constituent layer of the refrigerant-transporting hose according to claim 1 .
5. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, the semi-aromatic polyamide resin (A) forms a matrix phase and the aliphatic polyamide resin (B) containing the uncrosslinked elastomer (C) forms an island phase.
6. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, the elastomer (C) is incorporated as particles having an average particle diameter of 0.1 to 1 μm.
7. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, a content of the component (C) is 10 to 40 wt % of a total amount of the component (B) and the component (C).
8. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, a content of the component (A) is 60 to 90 wt % of a total amount of the resin composition for the refrigerant-transporting hose.
9. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, the aliphatic polyamide resin (B) comprises at least one selected from the group consisting of a polyamide 46 (PA46), a polyamide 6 (PA6), a polyamide 66 (PA66), a polyamide 92 (PA92), a polyamide 99 (PA99), a polyamide 610 (PA610), a polyamide 612 (PA612), a polyamide 11 (PA11), a polyamide 912 (PA912), a polyamide 12 (PA12), a copolymer of the polyamide 6 and the polyamide 66 (PA6/66), and a copolymer of the polyamide 6 and the polyamide 12 (PA6/12).
10. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, the elastomer (C) comprises at least one elastomer selected from the group consisting of styrene-, olefin-, vinyl chloride-, polyester-, polyurethane-, and polyamide-based elastomers.
11. A refrigerant-transporting hose according to claim 1 , wherein, in the resin composition, the elastomer (C) is incorporated substantially into the aliphatic polyamide resin (B) dispersed in a phase formed of the semi-aromatic polyamide resin (A).
12. A refrigerant-transporting hose according to claim 1 , wherein the constituent layer formed of the resin composition has a thickness of 0.15 to 0.2 mm.
13. A method of producing a resin composition for a refrigerant-transporting hose, the method comprising:
kneading an aliphatic polyamide resin (B) and an elastomer (C) that is not crosslinked to finely disperse the elastomer (C) in the aliphatic polyamide resin (B); and
mixing the kneaded product and a semi-aromatic polyamide resin (A) so as to obtain the resin composition for the refrigerant-transporting hose according to claim 1 , which contains the semi-aromatic polyamide resin (A) as a main component, and in which the aliphatic polyamide resin (B) is dispersed in a phase formed of the semi-aromatic polyamide resin (A) and the uncrosslinked elastomer (C) is incorporated in the form of particles into the dispersed component (B).
14. A method of producing a resin composition for a refrigerant-transporting hose according to claim 13 ,
wherein the kneading comprises kneading the aliphatic polyamide resin (B) and the uncrosslinked elastomer (C) at a temperature in a range of 200 to 250° C. to finely disperse the elastomer (C) in the aliphatic polyamide resin (B), and the mixing comprises melting and mixing the kneaded product and the semi-aromatic polyamide resin (A) at a temperature in a range of 260 to 310° C.