Nanoclay-based solid sorbents for carbon dioxide capture
A nanoclay based solid sorbent is provided having a nanoclay with at least one surface, and at least one amine containing compound wherein the amine containing compound is attached to the surface, as well as a method of making it. A method of capturing carbon dioxide gas is disclosed includes passing a gas from an effluent process stream containing carbon dioxide through the nanoclay based solid sorbent and capturing the carbon dioxide gas on the surface and within the nanoclay based solid sorbent. The nanoclay based solid sorbent having the captured carbon dioxide gas is regenerated by undergoing one or more cycles of desorption of the captured carbon dioxide gas from the nanoclay. The regenerated nanoclay based solid sorbent may then be reused.
1. A regenerative nanoclay based solid sorbent consisting essentially of:
a layered nanoclay with at least one surface, and
at least one amine containing compound that is immobilized to the surface of said nanoclay by coating the substantial entirety of said surface forming an immobilized amine, wherein said immobilized amine is easily removable from said surface of said nanoclay by washing or frictional mechanical means; and
at least another amine containing compound that is grafted onto the at least one surface of said nanoclay, wherein said grafted amine compound is not easily removable from said surface of said nanoclay by washing or frictional mechanical means, wherein said grafted amine compound is selected from the group consisting of an organoamine and an aminosilane, wherein said surface of said nanoclay includes at least one of an edge of a platelet of said nanoclay, an interior portion of said nanoclay, and an exterior portion of said nanoclay, and at least one edge of a platelet, an interior portion, and an exterior portion of each layer of said nanoclay, wherein said layered nanoclay adsorbs carbon dioxide at a temperature ranging from 50° C. to 85° C. and desorbs carbon dioxide in the presence of carbon dioxide at a temperature ranging from 100° C. to 155° C. for a resultant multiple cycle regenerative nanoclay based solid sorbent for producing a pure carbon dioxide stream, and wherein said layered nanoclay has a sustainable carbon dioxide capacity of at least 85 percent of an initial carbon dioxide capacity after three cycles of regeneration, wherein said nanoclay is selected from the group consisting of a montmorillonite, a bentonite, a kaolinite, a halloysite, and a synthetic nanoclay.
2. The nanoclay based solid sorbent of claim 1 wherein said synthetic nanoclay is a mixed-metal hydroxide nanoclay.
3. The nanoclay based solid sorbent of claim 1 wherein said synthetic nanoclay is a layered double hydroxide nanoclay.
4. The nanoclay based solid sorbent of claim 1 wherein said synthetic nanoclay is selected from the group consisting of a laponite, a hectorite, a saponite, an indonite, and a sepiocite.
5. The nanoclay based solid sorbent of claim 1 wherein said organoamine is a polyamine.
6. The nanoclay based solid sorbent of claim 1 wherein said aminosilane is selected from the group consisting of an aminopropyltrimethoxysilane, an amiopropyltrimethoxysilane, a N-3-trimethoxysilyl-propyl-ethylenediamine, a N-3-trimethoxysilyl-propyl-diethylenediamine, an ethylhydroxylaminopropyl-trimethoxysilane, and a diethylhydroxyl-aminopropyltrimethoxysilane.
7. The nanoclay based solid sorbent of claim 1 wherein said organoamine is polyethyleneimine.
8. The nanoclay based solid sorbent of claim 1 wherein said amine containing compound that is grafted onto said surface of said nanoclay is selected from the group consisting of an aminopropyltrimethoxysilane, an amiopropyltrimethoxysilane, a N-3-trimethoxysilyl-propyl-ethylenediamine, a N-3-trimethoxysilyl-propyl-diethylenediamine, an ethylhydroxylaminopropyl-trimethoxysilane, and a diethylhydroxyl-aminopropyltrimethoxysilane.
9. The nanoclay based solid sorbent of claim 1 wherein said amine containing compound that is immobilized onto said surface of said nanoclay is polyethyleneimine.
10. The nanoclay based solid of claim 1 wherein said amine containing compound that is grafted onto said surface of said nanoclay is aminopropyltrimethoxysilane, and wherein said amine containing compound that is immobilized onto said surface of said nanoclay is polyethyleneimine.
11. The nanoclay based solid sorbent of claim 1 , wherein said layered nanoclay adsorbs carbon dioxide at 85° C.