Organic Electroluminescent Device With Delayed Fluorescence
Novel electroluminescent devices containing bicarbazole triazine compounds as emissive dopants are described. Devices incorporating this class of compounds exhibit delayed fluorescence characteristics that showed EQE's far exceeding the theoretical limit for a conventional fluorescent device.
1 . A first device comprising a first organic light emitting device, further comprising:
an anode;
a cathode; and
an emissive layer, disposed between the anode and the cathode, comprising a first emissive dopant;
wherein the first emissive dopant comprises a compound having the formula:
wherein R 2 and R 3 represent mono-, di-, or tri-substitution, or no substitution;
wherein R 1 and R 4 represent mono-, di-, tri-, or tetra-substitution, or no substitution;
wherein R 1 , R 2 , R 3, and R 4 are independently selected from the group consisting of hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acids, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof;
wherein Ar 1 , Ar 2 , and Ar 3 are independently selected from aryl or heteroaryl and can be further substituted; and
wherein X is C or N.
2 . The first device of claim 1 , wherein the first emissive dopant is a delayed fluorescence emissive dopant.
3 . The first device of claim 1 , wherein Ar 1 , Ar 2 , and Ar 3 are further substituted.
4 . The first device of claim 1 , wherein Ar 1 , Ar 2 , and Ar 3 are independently selected from the group consisting of phenyl, pyridine, naphthalene, biphenyl, terphenyl, fluorene, dibenzofuran, dibenzothiophene, phenanthrene, and triphenylene; and
wherein Ar 1 , Ar 2 , and Ar 3 are independently further substituted with a substituent selected from the group consisting of hydrogen, alkyl, alkoxy, amino, alkenyl, alkynyl, aryl and heteroaryl, wherein the substituent is not an aryl or heteroaryl fused directly to Ar 1 , Ar 2 , and Ar 3 .
5 . The first device of claim 1 , wherein Ar 1 and Ar 2 are independently selected from the group consisting of phenyl, pyridine, and naphthalene.
6 . The first device of claim 1 , wherein Ar 3 is selected from the group consisting of phenyl, biphenyl, dibenzofuran, and dibenzothiophene.
7 . The first device of claim 1 , wherein R 1 is hydrogen.
8 . The first device of claim 1 , wherein R 1 , R 2 , R 3, and R 4 are hydrogen.
9 . The first device of claim 1 , wherein the compound is selected from the group consisting of:
10 . The first device of claim 1 , wherein the first device has a maximum external quantum efficiency of at least 10%.
11 . The first device of claim 1 , wherein the first device has a maximum external quantum efficiency of at least 15%.
12 . The first device of claim 1 , wherein the first device has an external quantum efficiency of at least 10% at 1000 nits.
13 . The first device of claim 1 , wherein the first device has an external quantum efficiency of at least 15% at 1000 nits.
14 . The first device of claim 1 , wherein the emissive layer further comprises a first phosphorescent emitting material.
15 . The first device of claim 14 , wherein first device emits a white light at room temperature when a voltage is applied across the organic light emitting device.
16 . The first device of claim 15 , wherein the first emissive dopant emits a blue light having a peak wavelength between about 400 nm to about 500 nm.
17 . The first device of claim 15 , wherein the first emissive dopant emits a yellow light having a peak wavelength between about 530 nm to about 580 nm.
18 . The first device of claim 14 , wherein the emissive layer further comprises a second phosphorescent emitting material.
19 . The first device of claim 1 , wherein the emissive layer further comprises a host compound.
20 . The first device of claim 1 , wherein the first device comprises a second organic light-emitting device;
wherein the second organic light emitting device is stacked on the first organic light emitting device.
21 . The first device of claim 1 , wherein the first device is a consumer product.
22 . The first device of claim 1 , wherein the first device is an organic light-emitting device.
23 . The first device of claim 1 , wherein the first device is a lighting panel.