Cured perfluoroelastomer article
View Patent ↗Cured perfluoroelastomers that contain high levels (i.e. greater than 50 phr) BaSO 4 exhibit good thermal sealing performance such as reduced sticking and reduced tendency for splitting.
1. A cured perfluoroelastomer article comprising
A) a perfluoroelastomer comprising copolymerized units of:
i) 15 to 60 mole percent perfluoro(alkyl vinyl ether),
ii) 0.1 to 5 mole percent of a cure site monomer having nitrile groups, and
iii) the remaining copolymerized units being of tetrafluoroethylene so that total mole percent of i+ii+iii is 100; and
B) greater than 60 parts by weight of BaSO 4 per hundred parts by weight perfluoroelastomer.
2. The cured perfluoroelastomer article of claim 1 comprising 70 to 100 parts by weight, per hundred parts by weight perfluoroelastomer, of BaSO 4 .
3. The cured perfluoroelastomer article of claim 1 wherein said BaSO 4 has an average particle size of 0.5 to 5 microns.
4. The cured perfluoroelastomer article of claim 1 wherein the cure site monomer is selected from the group consisting of:
CF 2 ═CF—O(CF 2 ) n —CN
where n=2-12, preferably 2-6;
CF 2 ═CF—O[CF 2 —CFCF 3 —O] n —CF 2 —CFCF 3 —CN
where n=0-4, preferably 0-2;
CF 2 ═CF—[OCF 2 CFCF 3 ] x —O—(CF 2 ) n —CN
where x=1-2, and n=1-4;
CF 2 ═CF—O—(CF 2 ) n —O—CF(CF 3 )CN
where n=2-4;
CF 2 ═CFOCF 2 CF(CF 3 )OCF 2 CF 2 CN;
and combinations of these.