Method for the extraction and recovery of vanadium
A method ( 10 ) for the extraction and recovery of vanadium from its ores, the method ( 10 ) characterised by the steps of: (i) Acid leaching ( 12 ) of an ore containing vanadium and iron to extract vanadium and iron into solution; (ii) Passing the product ( 78 ) of the leach step (i) to a solid/liquid separation step ( 80 ); (iii) Passing the liquid product ( 82 ) of separation step (ii) to a solvent extraction step ( 14 ) in which vanadium and iron are extracted into an organic extractant from that liquid product; (iv) Passing the loaded organic extractant produced in step (iii) to a stripping step ( 16, 18 ) in which acid is used to selectively and sequentially strip the vanadium and iron from the organic extractant; and (v) Passing the vanadium containing strip solution of step (iv) to a recovery step ( 104 ).
1. A method for extraction and recovery of vanadium from its ores, the method comprising the steps of:
(i) acid leaching of an ore containing vanadium, titanium and iron to extract vanadium and iron into solution and to form a solid residue containing titanium;
(ii) passing said solution and said solid residue of leach step (i) to a solid/liquid separation step;
(iii) passing a liquid product of separation step (ii) to a solvent extraction step in which vanadium and iron are extracted into an organic extractant from that liquid product;
(iv) passing a loaded organic extractant produced in step (iii) to a stripping step in which acid is used to selectively and sequentially strip the vanadium and iron from the organic extractant;
(v) passing the vanadium containing strip solution of step (iv) to a recovery step; and wherein the acid leaching is conducted in the range of about 25° C. to 80° C. under atmospheric pressure.
2. The method according to claim 1 , wherein the acid leaching of step (i) is conducted using hydrochloric acid.
3. The method according to claim 2 , wherein the concentration of hydrochloric acid is within the range of about 20% to 32% w/w.
4. The method according to claim 1 , wherein the residence time of the acid leaching is between about 30 to 360 minutes.
5. The method according to claim 1 , wherein a solids content during acid leaching is about 20% w/w.
6. The method according to claim 1 , wherein the organic extractant of step (iii) contains a phosphine oxide.
7. The method according to claim 6 , wherein the extractant comprises about 40% v/v phosphine oxide and 60% v/v organic solvent.
8. The method according to claim 1 , wherein the aqueous to organic ratio during the solvent extraction step (iii) is between about 1:1 to 1:20.
9. The method according to claim 1 , wherein the aqueous to organic ratio during the solvent extraction step (iii) is about 1:5.
10. The method according to claim 1 , wherein the stripping step (iv) is conducted in a counter-current manner whereby vanadium is stripped from the loaded organic extractant prior to the stripping of iron from that solution.
11. The method according to claim 1 , wherein the acid used in the strip of step (iv) is hydrochloric acid.
12. The method according to claim 11 , wherein the hydrochloric acid is provided in a concentration of between about 2 to 4 M when stripping vanadium.
13. The method according to claim 11 , wherein the hydrochloric acid is provided in a concentration of about 0.01 M when stripping iron.
14. The method according to claim 1 , wherein the purity of a vanadium solution produced in the recovery step (v) is between about 76% to 95%.
15. The method according to claim 1 , wherein the purity of an iron solution produced in the recovery step (v) is about 99%.
16. A method for extraction and recovery of vanadium from its ores comprising the steps of:
(i) acid leaching of an ore containing vanadium, titanium and iron to extract vanadium and iron into solution and to form a solid residue containing titanium;
(ii) passing said solution and said solid residue of leach step (i) to a solid/liquid separation step;
(iii) extracting iron and vanadium from a liquid product of separation step (ii);
(iv) then stripping vanadium from an organic extractant formed in step (iii) to form a vanadium-containing strip solution;
(v) passing the vanadium-containing strip solution of step (iv) to a recovery step; and
wherein the acid leaching is conducted in the range of about 25° C. to 80° C. under atmospheric pressure.
17. The method of claim 1 , wherein greater than 0 and less than 20% by weight of the titanium is extracted into the solution after step (i).
18. The method of claim 16 , wherein greater than 0 and less than 20% by weight of the titanium is extracted into the solution after step (i).
19. The method of claim 1 , wherein 16-19% by weight of the titanium is extracted into the solution after step (i).
20. The method of claim 18 , wherein 16-19% by weight of the titanium is extracted into the solution after step (i).