Process for preparing polyurea microcapsules
The present invention relates to a process for producing perfume-containing microcapsules with a polyurea wall that can be used in home or personal care products, as well as to the microcapsules themselves and consumer products that contain these microcapsules. The process of the invention uses a combination of aromatic and aliphatic polyisocyanates in specific relative concentrations.
1. A process for the preparation of polyurea microcapsules for use in a consumer product, which process comprises:
dissolving a first mixture of at least one aliphatic polyisocyanate and at least one aromatic polyisocyanate, both having at least two isocyanate functional groups, in a perfume to form a first solution with the aliphatic and aromatic polyisocyanates present in a molar ratio ranging from 80:20 to 10:90;
adding to the first solution an aqueous solution that includes an emulsifier or a colloidal stabilizer to form a second mixture; and
adding to the second mixture a polyamine to form with the polyisocyanate a slurry of microcapsules having a polyurea wall encapsulating the perfume therein in order to obtain microcapsules that exhibit less perfume leakage during storage in a consumer product that includes a surfactant and better odor performance during use of the consumer product that contains the microcapsules compared to a consumer product containing a surfactant and polyurea microcapsules made without the recited mixture of polyisocyanates.
2. The process according to claim 1 , which further comprises forming a powder of polyurea microcapsules by drying the slurry of microcapsules.
3. The process according to claim 1 , wherein the perfume is present in an amount of between 25 and 60% by weight relative to the total weight of the slurry of microcapsules.
4. The process according to claim 1 , wherein the aromatic polyisocyanate comprises a phenyl, a toluyl, a xylyl, a naphthyl or a diphenyl moiety.
5. The process according to claim 1 , wherein the aromatic polyisocyanate is selected from the group consisting of a polyisocyanurate of toluene diisocyanate, a trimethylol propane-adduct of toluene diisocyanate and a trimethylol propane-adduct of xylylene diisocyanate.
6. The process according to claim 1 , wherein the aliphatic polyisocyanate is selected from the group consisting of a trimer of hexamethylene diisocyanate, a trimer of isophorone diisocyanate and a biuret of hexamethylene diisocyanate.
7. The process according to claim 1 , wherein first mixture comprises a mixture of a biuret of hexamethylene diisocyanate with a trimethylol propane-adduct of xylylene diisocyanate.
8. The process according to claim 1 , wherein the aliphatic polyisocyanate and the aromatic polyisocyanate are present in a molar ratio of 60:40 to 20:80.
9. The process according to claim 1 , wherein the first mixture is present in an amount of between 2 and 20% by weight, relative to the total weight of the first solution.
10. The process according to claim 1 , wherein the colloidal stabilizer is polyvinyl alcohol, a cellulose derivative, polyethylene oxide, a copolymer of polyethylene oxide and polyethylene or polypropylene oxide, a copolymer of acrylamide and acrylic acid, a cationic polymer or a mixture thereof.
11. The process according to claim 1 , wherein the polyamine is selected from the group consisting of water soluble guanidine salts, guanidine, tris-(2-aminoethyl)amine, N,N,N′,N′-tetrakis(3-aminopropyl)-1,4-butanediamine and N,N′-bis(3-aminopropyl)-ethylenediamine.
12. The process according to claim 1 , wherein the aromatic polyisocyanate comprises a trimethylol propane-adduct of toluene diisocyanate and the aliphatic polyisocyanate comprises a biuret of hexamethylene diisocyanate.
13. Polyurea microcapsules obtained by the process according to claim 1 for use in a consumer product, which microcapsules exhibit less perfume leakage during storage in a consumer product that includes a surfactant and better odor performance during use of the consumer product that contains the microcapsules compared to a consumer product containing a surfactant and polyurea microcapsules made without the recited mixture of polyisocyanates.
14. A consumer product comprising a surfactant and microcapsules as defined in claim 13 .
15. The consumer product according to claim 14 in the form of a shampoo, a hair conditioner, a soap, a body wash or another hygiene product, a cosmetic preparation, a body lotion, a deodorant or antiperspirant, a perfume, an after-shave lotion, a cologne, a solid or liquid detergent, an all-purpose cleaner, a fabric softener or refresher, an ironing water or a detergent, softener or drier sheet.
16. Polyurea microcapsules for use in a consumer product, the microcapsules comprising:
a polyurea wall, which comprises the reaction product of the polymerisation between at least one polyisocyanate and at least one polyamine;
a colloidal stabilizer or an emulsifier; and
a perfume encapsuled within the polyurea wall;
wherein the polyisocyanate is in the form of a mixture of at least one aliphatic polyisocyanate and at least one aromatic polyisocyanate in a respective molar ratio comprised between 80:20 to 10:90, both the aromatic and the aliphatic polyisocyanate comprising at least two functional isocyanate groups; and
wherein the microcapsules exhibit less perfume leakage during storage in a consumer product that includes a surfactant and better odor performance during use of the microcapsules that contain the microcapsules compared to a consumer product containing a surfactant and polyurea microcapsules made without the recited mixture of polyisocyanates.
17. A consumer product comprising microcapsules as defined in claim 16 .
18. The consumer product according to claim 17 in the form of a shampoo, a hair conditioner, a soap, a body wash or another hygiene product, a cosmetic preparation, a body lotion, a deodorant or antiperspirant, a perfume, an after-shave lotion, a cologne, a solid or liquid detergent, an all-purpose cleaner, a fabric softener or refresher, an ironing water or a detergent, softener or drier sheet.
19. The microcapsules according to claim 16 , wherein the aromatic polyisocyanate comprises a trimethylol propane-adduct of toluene diisocyanate and the aliphatic polyisocyanate comprises a biuret of hexamethylene diisocyanate.
20. The consumer product according to claim 17 , wherein, in the microcapsules, the aromatic polyisocyanate comprises a trimethylol propane-adduct of toluene diisocyanate and the aliphatic polyisocyanate comprises a biuret of hexamethylene diisocyanate.