Silicon oxynitride film formation method and substrate equipped with silicon oxynitride film formed thereby
View Patent ↗The present invention provides a silicon oxynitride film formation method capable of reducing energy cost, and also provides a substrate equipped with a silicon oxynitride film formed thereby. This method comprises the steps of: casting a film-formable coating composition containing a polysilazane compound on a substrate surface to form a coat; drying the coat to remove excess of the solvent therein; and then irradiating the dried coat with UV light at a temperature lower than 150° C.
1. A silicon oxynitride film formation method comprising
a casting step in which a film-formable coating composition containing a polysilazane compound is cast on a substrate surface to form a coat,
a drying step in which the coat is dried to remove excess of the solvent therein, and
a UV irradiation step in which the dried coat is irradiated with UV light at a temperature lower than 150° C. in an inert atmosphere, wherein the irradiated energy of the UV light is 0.5 kJ/m 2 or more and the irradiation time is 30 minutes or more.
2. The method according to claim 1 , wherein the UV irradiation step is carried out at room temperature.
3. The method according to claim 1 , wherein the UV irradiation step is carried out without applying any external energy other than the UV light.
4. The method according to claim 1 , wherein the UV light is far UV light in the wavelength range of less than 200 nm.
5. The method according to claim 1 , wherein the coat has a thickness of 0.01 to 1.0 μm.
6. A substrate equipped with a silicon oxynitride film formed by the method according to claim 1 .
7. A resist pattern formation process in which a resist pattern is formed by photolithography,
wherein
the method according to claim 1 is used to form a bottom antireflective coating made of silicon oxynitride on the substrate-side surface of the resist layer.