Lithium Ion Cell
A lithium-ion cell includes a negative electrode, a positive electrode, and a separator arranged between the negative electrode and the positive electrode. In order to increase the mechanical stability of the separator and in the process to negatively influence the electrical power of the lithium-ion cell as little as possible, the separator includes at least one inorganic solid electrolyte layer conducting lithium ions.
1 . A lithium ion cell comprising:
a negative electrode;
a positive electrode; and
a separator arranged between the negative electrode and the positive electrode, and including at least one inorganic solid-state electrolyte layer which conducts lithium ions.
2 . The lithium ion cell as claimed in claim 1 , wherein the at least one inorganic solid-state electrolyte layer which conducts lithium ions does not conduct electrons.
3 . The lithium ion cell as claimed in claim 1 , wherein the at least one inorganic solid-state electrolyte layer which conducts lithium ions comprises at least one lithium ion-conducting compound selected from the group consisting of lithium ion-conducting compounds of the perovskite type, lithium ion-conducting compounds of the NASICON type, lithium ion-conducting compounds of the LiSICON type, lithium ion-conducting compounds of the thio-LiSICON type, lithium ion-conducting compounds of the garnet type, lithium ion-conducting composites, amorphous, inorganic lithium ion-conducting compounds, lithium ion-conducting compounds of the LiPON type, lithium ion-conducting compounds of the LiSON type, lithium ion-conducting compounds of the LiPOS type, lithium ion-conducting compounds of the LiBSO type, lithium ion-conducting compounds of the LiSIPON type, and mixtures thereof.
4 . The lithium ion cell as claimed in claim 1 , wherein the at least one inorganic solid-state electrolyte layer which conducts lithium ions includes at least one lithium lanthanide titanate of the perovskite type, having the general formula (1):
Li 3a Ln 0.67-a TiO 3 ,
where Ln is lanthanum, and 0.04≦a≦0.15.
5 . The lithium ion cell as claimed in claim 1 , wherein the at least one inorganic solid-state electrolyte layer which conducts lithium ions is porous and has a porosity of from ≧5% to ≦90%.
6 . The lithium ion cell as claimed in claim 1 , wherein the at least one inorganic solid-state electrolyte layer which conducts lithium ions has a lithium ion conductivity at room temperature of at least 5·10 −4 S/cm.
7 . The lithium ion cell as claimed in claim 1 , wherein the separator includes a layer system composed of at least one inorganic solid-state electrolyte layer which conducts lithium ions and at least one polymer layer.
8 . The lithium ion cell as claimed in claim 1 , wherein the separator includes at least one polymer layer which has an inorganic solid-state electrolyte layer that conducts lithium ions on at least the side facing the positive electrode.
9 . The lithium ion cell as claimed in claim 1 , wherein the negative electrode includes natural or synthetic graphite, carbon nanotubes, soft carbons and/or hard carbons, as an intercalation material.
10 . A separator for a lithium ion cell, comprising:
a layer system includes (i) at least one inorganic solid-state electrolyte layer which conducts lithium ions and (ii) at least one polymer layer.
11 . The separator as claimed in claim 10 , wherein:
the at least one inorganic solid-state electrolyte layer which conducts lithium ions includes a lithium ion-conducting compound
wherein the lithium ion-conducting compound is a lithium lanthanide titanate of the perovskite type, and
wherein the lithium ion-conducting compound has the general formula:
Li 3a Ln (2/3)-a□(1/3)-2a TiO 3 or Li 3a Ln 0.67-a TiO 3 ,
where Ln is lanthanum, and 0.04≦a≦0.15.
12 . The separator as claimed in claim 10 , wherein the separator is used in a lithium ion cell.