Systems and methods for removing finely dispersed particulate matter from a fluid stream
Disclosed herein are systems for removing particulate matter from a fluid, comprising a particle functionalized by attachment of at least one activating group or amine functional group, wherein the modified particle complexes with the particulate matter within the fluid to form a removable complex therein. The particulate matter has preferably been contacted, complexed or reacted with a tethering agent. The system is particularly advantageous to removing particulate matter from a fluid waste stream following mining or ore processing operations.
1. A method of removing particulate matter from a waste tailing fluid, comprising:
adding an activating material to the waste tailing fluid comprising the particulate matter, wherein the activating material affixes to the particulate matter to form an activated particle, and wherein the activating material is an anionic partially hydrolyzed polyacrylamide;
attaching a tethering material to an anchor particle to form a tether-bearing anchor particle, wherein the tethering material is a cationic polymer;
adding the tether-bearing anchor particle to the fluid comprising the activated particle, wherein the tethering material attaches to the activated particle to form a removable complex in the fluid, wherein the removable complex comprises the particulate matter and the anchor particle;
removing the removable complex from the fluid, thereby removing the particulate matter from the waste tailing fluid;
wherein the fluid is a waste tailing fluid derived from energy production or a mining process.
2. The method of claim 1 , wherein the mining process is coal mining.
3. The method of claim 1 , wherein the mining process is the mining of an inorganic ore.
4. The method of claim 1 , wherein the mining process is the processing or beneficiation of an ore.
5. The method of claim 4 , wherein the ore is selected from the group consisting of iron, trona, phosphate, kaolin, bauxite and potash.
6. The method of claim 1 , wherein the particulate matter is selected from the group consisting of coal combustion products, coal fines, clay particles and mineral particles.
7. The method of claim 1 , wherein the particulate matter has a mass mean diameter less than about 50 microns.
8. The method of claim 1 , wherein the fluid is selected from the group consisting of red mud fluid stream, gangue, slurry containing fine particulate kaolin, tailings from trona mining and slurry produced by phosphate beneficiation.
9. The method of claim 1 , wherein the removable complex is removed by a process selected from the group consisting of filtration, centrifugation or gravitational settling.
10. The method of claim 1 , wherein the anchor particle comprises sand.
11. The method of claim 1 , wherein the tethering material is selected from the group consisting of chitosan, lupamin, branched polyethyleneimine (BPEI), and polydimethyldiallylammonium chloride (PDAC).
12. The method of claim 1 , wherein the particulate matter comprises quartz, clay fines or a combination thereof.
13. The method of claim 1 , wherein the anchor particle comprises a material indigenous to a mining process.
14. The method of claim 1 , wherein the tethering material is a polymer with quaternary ammonium groups.
15. The method of claim 1 , wherein the tethering material is selected from the group consisting of epichlorohydrin dimethylamine (epi/DMA), styrene maleic anhydride imide (SMAI), polyethylene imide (PEI), polyvinylamine, polyallylamine, amine-aldehyde condensates, poly(dimethylaminoethyl acrylate methyl chloride quaternary) polymers and polydimethyldiallylammonium chloride (PDAC).
16. The method of claim 1 , wherein the anchor particle has a larger diameter than that of the particulate matter.
17. The method of claim 16 , wherein the anchor particle has a mass mean diameter of greater than 70 microns.
18. The method of claim 1 , wherein the anchor particle is made from recycled materials or waste.
19. The method of claim 1 , wherein the anchor particle comprises a material selected from the group consisting of calcium carbonate, dolomite, calcium sulfate, kaolin, talc, titanium dioxide, sand, diatomaceous earth, aluminum hydroxide, silica, and metal oxides.
20. A method for removing coal fines from a fluid, comprising:
adding an activator polymer to a population of coal fines suspended in a fluid to form activated coal fines, wherein the activator polymer is an anionic partially hydrolyzed polyacrylamide;
complexing an anchor particle with a tethering agent thereby forming tether-bearing anchor particles, wherein the tethering agent is a cationic polymer;
mixing the tether-bearing anchor particles with the activated coal fines, wherein the tethering material attaches to the activated coal fines to form a complex removable from the fluid, and further wherein the complex comprises a composite material comprising the coal fines and the anchor particles; and
removing the composite material from the fluid.
21. The method of claim 20 , wherein the anchor particle comprises coal.
22. The method of claim 20 , wherein the anchor particle is combustible or comprises a non-combustible material.
23. The method of claim 20 , wherein the tethering material is polydiallyldimethylammonium chloride (pDADMAC).