Fabrication and use of carbon-coated silicon monoxide for lithium-ion batteries
The present invention provides anode materials, methods of producing them, anodes, methods of producing them, electrochemical cells, and lithium-ion batteries, where the anode material comprises a silicon monoxide nanoparticle. In certain embodiments, the silicon monoxide is porous or mesoporous. In certain embodiments, the porous or mesoporous silicon additionally comprises other materials within its pores, such as lithium.
1. An anode material, for mixing with a binder into a slurry during fabrication of a negative electrode of a lithium ion battery, the anode material comprising:
nanoparticles, forming agglomerates, in a powder form,
wherein each of the nanoparticles comprises a carbon-containing outer phase and a silicon monoxide inner phase,
wherein the carbon-containing outer phase is covalently bonded to the silicon monoxide inner phase, and
wherein the agglomerates comprise pores, having an average pore diameter from about 1 nm to 500 nm and disposed between the nanoparticles in the agglomerates.
2. The anode material of claim 1 , wherein the nanoparticles have a particle diameter of from about 50 nm to 250 nm.
3. The anode material of claim 1 , wherein the carbon-containing outer phase comprises an alkyl group or a hydroxyalkyl group, and the alkyl group or the hydroxyalkyl group is covalently bonded to the silicon monoxide inner phase.
4. The anode material of claim 1 , wherein the nanoparticles have a particle diameter of from about 60 nm to 200 nm.
5. The anode material of claim 1 , wherein the nanoparticles have a particle diameter of from about 70 nm to 175 nm.
6. The anode material of claim 1 , wherein the nanoparticles have a particle diameter of from about 80 nm to 150 nm.
7. The anode material of claim 1 , wherein the nanoparticles have a particle diameter of from about 90 nm to 125 nm.
8. The anode material of claim 1 , wherein the nanoparticles are porous.
9. The anode material of claim 1 , wherein the carbon-containing outer phase comprises an ethyl group.
10. The anode material of claim 1 , wherein the carbon-containing outer phase comprises a propyl group.
11. The anode material of claim 1 , wherein the carbon-containing outer phase comprises an alkyl ether.
12. The anode material of claim 11 , wherein the alkyl ether of the carbon-containing outer phase comprises one of a C 1-6 alkoxy group, a C 1-8 alkoxy group, a C 1-12 alkoxy group, or a hydroxyalkoxy group.
13. The anode material of claim 11 , wherein the alkyl ether of the carbon-containing outer phase comprises a C 2-3 alkoxy group.
14. The anode material of claim 11 , wherein the alkyl ether of the carbon-containing outer phase is derived from one of methanol, ethanol, propanol, isopropanol, butanol, or 2-butanol.
15. The anode material of claim 11 , wherein the alkyl ether of the carbon-containing outer phase is derived from one of ethylene glycol or 1,3-propanediol.
16. The anode material of claim 1 , wherein the anode material is substantially free from polyvinylidene fluoride (PVDF).
17. The anode material of claim 1 , wherein the nanoparticles are substantially free from silicon dioxide.
18. The anode material of claim 1 , the carbon-containing outer phase consists essentially of an alkyl group or a hydroxyalkyl group.
19. The anode material of claim 1 , wherein the pores have the average pore diameter from about 10 nm to 400 nm.
20. The anode material of claim 1 , wherein the pores have the average pore diameter from about 25 nm to 325 nm.
21. The anode material of claim 1 , wherein the pores have the average pore diameter from about 50 nm to 250 nm.
22. The anode material of claim 1 , wherein the pores have the average pore diameter from about 60 nm to 200 nm.
23. The anode material of claim 1 , wherein the pores have the average pore diameter from about 70 nm to 175 nm.
24. The anode material of claim 1 , wherein the pores have the average pore diameter from about 80 nm to 150 nm.
25. The anode material of claim 1 , wherein the pores have the average pore diameter from about 90 nm to 125 nm.