Method for synthesis of lactic acid and its derivatives
A method for synthesis of lactic acid and its derivatives is provided. First, a mixture is prepared, which includes: at least one carbohydrate-containing raw material, at least one alcohol, at least one composite catalyst containing metal chloride(s) (MCl n ) and tin-containing compound(s), and at least one solvent, wherein M is selected from a group consisting of Li + , Na + K + , Mg 2+ , Ca 2+ , Sr 2+ , Ga 3+ , In 3+ , Sb 3+ , Bi 3+ , Cr 3+ , Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ , Zn 2+ , and n represents 1, 2 or 3. Then, the mixture is heated to obtain lactic acid and its derivatives. By using the above catalyst and method, it is capable of converting carbohydrate-containing raw material to lactic acid and its derivatives directly in a more efficient and economical way.
1. A method for synthesis of lactic acid and its derivatives, comprising:
providing a mixture, comprising: at least one carbohydrate-containing raw material, at least one alcohol, at least one composite catalyst containing metal chloride(s) (MCln) and tin-containing compound(s), and at least one solvent, wherein M is selected from a group consisting of Li + , Na + K + , Mg 2+ , Ca 2+ , Sr 2+ , Ga 3+ , In 3+ , Sb 3+ , Bi 3+ , Cr 3+ , Mn 2+ , Fe 2+ , Co 2+ , Ni 2+ , Zn 2+ , and n represents 1, 2 or 3, and the at least one solvent comprises the methyl esters of C8 to C22 fatty acids; and
heating the mixture to obtain lactic acid and its derivatives.
2. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the tin-containing compound(s) comprises at least one of Sn 4+ and Sn 2+ .
3. The method for synthesis of lactic acid and its derivatives of claim 2 , wherein the anion of the tin-containing compound(s) is selected from a group consisting of F − , Cl − , Br − , I − , HSO 4 − , CH 3 SO 3 − , C 6 H 5 SO 3 − , H 2 PO 4 − , HPO 4 2− , PO 4 3− , PF 6 − , BO 2 − , BF 4 − , SiF 6 2− and CH 3 CO 2 − .
4. The method for synthesis of lactic acid and its derivatives of claim 3 , wherein the tin-containing compound(s) is SnCl 2 .
5. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the carbohydrate-containing raw material is at least one of polysaccharide and monosaccharide.
6. The method for synthesis of lactic acid and its derivatives of claim 5 , wherein the carbohydrate-containing raw material is at least one selected from a group consisting of cellulose, starch, glucosan, sucrose, fructose and glucose.
7. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the alcohol is selected from the group consisting of monohydric alcohols, dihydric alcohols, and polyhydric alcohols.
8. The method for synthesis of lactic acid and its derivatives of claim 7 , wherein the alcohol is monohydric alcohol, and the monohydric alcohol is selected from a group consisting of methanol, ethanol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, and tert-butanol.
9. The method for synthesis of lactic acid and its derivatives of claim 7 , wherein the alcohol is dihydric alcohol, and the dihydric alcohol is selected from the group consisting of ethylene glycol, 1,2-propandiol, and 1,3-propandiol.
10. The method for synthesis of lactic acid and its derivatives of claim 7 , wherein the alcohol is polyhydric alcohol, and the polyhydric alcohol is glycerol.
11. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the composite catalyst is a composite of NaCl and SnCl 2 .
12. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the composite catalyst is a composite of MgCl 2 and SnCl 2 .
13. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the composite catalyst is a composite of CaCl 2 and SnCl 2 .
14. The method for synthesis of lactic acid and its derivatives of claim 1 , wherein the solvent further comprises water, and alcohols.
15. The method for synthesis of lactic acid and its derivatives of claim 14 , wherein the alcohols is selected from a group consisting of alcohol, 1-propanol, 2-propanol, 1-butanol, 2-butanol, tert-butanol, 1,2-propanediol, 1,3-propanediol and glycerol.
16. The method for synthesis of lactic acid and its derivatives of claim 4 , wherein a reaction temperature of the heating step is between 50 and 200° C.
17. The method for synthesis of lactic acid and its derivatives of claim 16 , wherein the reaction temperature of the heating step is between 80 and 180° C.