Aqueous inkjet inks containing polymeric binders with components to interact with cellulose
View Patent ↗Disclosed are aqueous inkjet inks containing a polymeric ink additive as a binder. The binder contains a component capable of interacting with cellulose. Certain heterocycles having similar Hansen solubility parameters as cellulose were incorporated into the polymeric binders. Prints from these inks have better durability and optical properties than similar additives that do not have the components capable of interacting with cellulose.
1. An aqueous inkjet ink comprising a colorant, an aqueous vehicle, and an polymeric ink additive as a binder, wherein said polymeric ink additive is a random or structured polymer and comprises at least three monomers A, B and C; wherein
(a) monomer A is a hydrophobic acrylate monomer;
(b) monomer B is a hydrophilic acrylic monomer; and
(c) monomer C is an acrylate monomer with the O atom on the ester bonding, either directly or via a linking group containing 1-10 carbon atoms, to a carbon or heteroatom of a monocyclic or bicyclic heterocycle containing N, S or O atoms on the ring, wherein said heterocycle is selected from the group consisting of imidazole, imidazolidinone, oxazolidinone, thiazolidinone, benzotriazole, benzimidazole, triazole, benzotriazole, thiazole, benzothiazole, pyrimidine, pyridazine and glycoside, and wherein the carbon atoms on the ring of said heterocycle are optionally substituted with one or more R 1 , OR 2 , SR 2 or NR 3 R 4 , and the N atom or atoms on the ring of said heterocycle are optionally substituted with R 1 or —R 5 OR 2 ;
each R 1 is independently C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl;
each R 2 is independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl; and
each R 3 and R 4 are independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl; and
each R 5 is C 1 -C 5 alkyl.
2. The ink of claim 1 , wherein said polymeric ink additive contains between 10 to 80% by weight of monomer A, between 5 to 50% by weight of monomer B, and between 5 to 50% by weight of monomer C.
3. The ink of claim 1 , wherein said polymeric ink additive has an acid number (mg KOH per gram solid polymer) of at least 10 and at most 250.
4. The ink of claim 1 , wherein said polymeric ink additive has a number average molecular weight of between 2,000 and 30,000 daltons.
5. The ink of claim 1 , wherein said colorant is a pigment.
6. The ink of claim 1 , wherein said colorant is a dispersed dye.
7. The ink of claim 5 , wherein said colorant is a self-dispersed pigment.
8. The ink of claim 7 , wherein said self-dispersed pigment comprises anionic hydrophilic groups.
9. The ink of claim 8 , wherein said anionic hydrophilic groups are carboxyl groups.
10. The ink of claim 1 , wherein said heterocycle is imidazole.
11. The ink of claim 1 , wherein said heterocycle is imidazolidinone.
12. The ink of claim 1 , wherein said heterocycle is oxazolidinone.
13. The ink of claim 1 , wherein said heterocycle is thiazolidinone.
14. The ink of claim 1 , wherein said heterocycle is benzotriazole.
15. The ink of claim 1 , wherein said heterocycle is glycoside.
16. A method of inkjet printing onto a substrate is provided, comprising, in any workable order, the steps of: (a) providing an inkjet printer that is responsive to digital data signals; (b) loading the printer with a substrate to be printed; (c) loading the printer with the aqueous inkjet ink of claim 1 ; and (d) printing onto the substrate using the aqueous inkjet ink, in response to the digital data signals to form a printed image on the substrate.
17. An inkjet ink set wherein at least one of the inks in the inkjet ink set is comprised of a colorant, an aqueous vehicle, and an polymeric ink additive as a binder, wherein said polymeric ink additive is a random or structured polymer and comprises at least three monomers A, B and C; wherein
(a) monomer A is a hydrophobic acrylate monomer;
(b) monomer B is a hydrophilic acrylic monomer; and
(c) monomer C is an acrylate monomer with the O atom on the ester bonding, either directly or via a linking group containing 1-10 carbon atoms, to a carbon or heteroatom of a monocyclic or bicyclic heterocycle containing N, S or O atoms on the ring, wherein said heterocycle is selected from the group consisting of imidazole, imidazolidinone, oxazolidinone, thiazolidinone, benzotriazole, benzimidazole, triazole, benzotriazole, thiazole, benzothiazole, pyrimidine, pyridazine and glycoside, and wherein the carbon atoms on the ring of said heterocycle are optionally substituted with one or more R 1 , OR 2 , SR 2 or NR 3 R 4 , and the N atom or atoms on the ring of said heterocycle are optionally substituted with R 1 or —R 5 OR 2 ;
each R 1 is independently C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl;
each R 2 is independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl; and
each R 3 and R 4 are independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl; and
each R 5 is C 1 -C 5 alkyl.
18. A method of inkjet printing onto a substrate is provided, comprising, in any workable order, the steps of: (a) providing an inkjet printer that is responsive to digital data signals; (b) loading the printer with a substrate to be printed; (c) loading the printer with the inkjet ink set of claim 17 ; and (d) printing onto the substrate using the inkjet ink set, in response to the digital data signals to form a printed image on the substrate.