Aqueous inkjet inks containing polyurethane binders with components to interact with cellulose

1. An aqueous inkjet ink comprising a colorant, an aqueous vehicle, and a polyurethane ink additive as a binder, wherein said polyurethane additive comprises at least one compound of the general structure of Formula I:

each Y is independently O, S or NR 4 ;

each W is N, O or S;

n is an integer from 2 to 30;

each R 1 is independently C 1 -C 20 alkyl optionally substituted with one or more R 5 , OR 6 , SR 6 or NR 7 R 8 , or C 6 -C 40 aryl optionally substituted with one or more R 5 , OR 6 , SR 6 or NR 7 R 8 ;

each R 2 is comprised of difunctional isocyanate reactants Z 1 , Z 2 and Z 3 , wherein

Z 1 is a difunctional isocyanate reactant substituted with an aqueous dispersing ionic group, and Z 1 is present in between 5 to 40 weight percent of total weight of the polyurethane dispersant;

Z 2 is a difunctional or trifunctional isocyanate reactant selected from the group consisting of diol, diamine, amino alcohol, diamino alcohol, and amino dialcohol, and

Z 2 is present in between 0 to 40 weight percent of total weight of the polyurethane dispersant; and

Z 3 is a difunctional isocyanate reactant substituted with R 3 , and Z 3 is present in between 5 to 40 weight percent of total weight of the polyurethane dispersant; and

each R 3 is independently a monocylic or bicyclic heterocycle containing N, S or O atoms on the ring bonding via a carbon or heteroatom to Y or Z 2 either directly or via a linking group containing 1-10 carbon atoms, wherein said heterocycle is selected from the group consisting of imidazole, imidazolidinone, oxazolidinone, thiazolidinone, benzotriazole, benzimidazole, triazole, benzotriazole, thiazole, benzothiazole, pyrimidine, pyridazine, pyrrolidone and glycoside, and wherein the carbon atoms on the ring of said heterocycle are optionally substituted with one or more R 5 , OR 6 , SR 6 or NR 7 R 8 , and the N atom or atoms on the ring of said heterocycle are optionally substituted with R 5 or —R 9 OR 6 ;

each R 5 is independently C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl;

each R 6 is independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl; and

each R 7 and R 8 are independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl;

and each R 9 is C 1 -C 5 alkyl.

2. The ink of claim 1 wherein R 2 further comprises Z 4 , and Z 4 is a difunctional or trifunctional isocyanate reactant selected from the group consisting of a diol that contains a sulfone and a diamine that contains a sulfone.

3. The ink of claim 1 wherein said polyurethane ink additive has an acid number (mg KOH per gram solid polymer) of at least 10 and at most 250.

4. The ink of claim 1 , wherein said polyurethane ink additive has a number average molecular weight of between 2,000 and 30,000 daltons.

5. The ink of claim 1 wherein said colorant is a pigment.

6. The ink of claim 1 wherein said colorant is a dispersed dye.

7. The ink of claim 5 wherein said colorant is a self-dispersed pigment.

8. The ink of claim 7 wherein said self-dispersed pigment comprises anionic hydrophilic groups.

9. The ink of claim 1 wherein said anionic hydrophilic groups are carboxyl groups.

10. The aqueous pigment dispersion of claim 1 wherein R 3 is independently a monocylic or bicyclic heterocycle.

11. The ink of claim 1 wherein said heterocycle is oxazolidinone.

12. The ink of claim 1 wherein said heterocycle is imidazole.

13. The ink of claim 1 wherein said heterocycle is imidazolidinone.

14. The ink of claim 1 wherein said heterocycle is thiazole.

15. The ink of claim 1 wherein said heterocycle is pyrimidine.

16. The ink of claim 1 wherein said heterocycle is pyridazine.

17. The ink of claim 1 wherein said heterocycle is glycoside.

18. The ink of claim 1 wherein said heterocycle is pyrrolidone.

19. An inkjet ink set wherein at least one of the inks in the inkjet ink set is comprised of a colorant, an aqueous vehicle, and a polyurethane ink additive as a binder, wherein said polyurethane additive comprises at least one compound of the general structure of Formula I:

each Y is independently O, S or NR 4 ;

each W is N, O or S;

n is an integer from 2 to 30;

each R 1 is independently C 1 -C 20 alkyl optionally substituted with one or more R 5 , OR 6 , SR 6 or NR 7 R 8 , or C 6 -C 40 aryl optionally substituted with one or more R 5 , OR 6 , SR 6 or NR 7 R 8 ;

each R 2 is comprised of difunctional isocyanate reactants Z 1 , Z 2 and Z 3 , wherein

Z 1 is a difunctional isocyanate reactant substituted with an aqueous dispersing ionic group, and Z 1 is present in between 5 to 40 weight percent of total weight of the polyurethane dispersant;

Z 2 is a difunctional or trifunctional isocyanate reactant selected from the group consisting of diol, diamine, amino alcohol, diamino alcohol, and amino dialcohol, and Z 2 is present in between 0 to 40 weight percent of total weight of the polyurethane dispersant; and

Z 3 is a difunctional isocyanate reactant substituted with R 3 , and Z 3 is present in between 5 to 40 weight percent of total weight of the polyurethane dispersant; and

each R 3 is independently a monocylic or bicyclic heterocycle containing N, S or O atoms on the ring bonding via a carbon or heteroatom to Y or Z 2 either directly or via a linking group containing 1-10 carbon atoms, wherein said heterocycle is selected from the group consisting of imidazole, imidazolidinone, oxazolidinone, thiazolidinone, benzotriazole, benzimidazole, triazole, benzotriazole, thiazole, benzothiazole, pyrimidine, pyridazine, pyrrolidone and glycoside, and wherein the carbon atoms on the ring of said heterocycle are optionally substituted with one or more R 5 , OR 6 , SR 6 or NR 7 R 8 , and the N atom or atoms on the ring of said heterocycle are optionally substituted with R 5 or —R 9 OR 6 ;

each R 5 is independently C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl;

each R 6 is independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl; and

each R 7 and R 8 are independently H, C 1 -C 20 alkyl, C 3 -C 20 cycloalkyl or C 6 -C 40 aryl;

and each R 9 is C 1 -C 5 alkyl.

20. A method of inkjet printing onto a substrate comprising, in any workable order, the steps of:

(e) providing an inkjet printer that is responsive to digital data signals;

(t) loading the printer with a substrate to be printed;

(g) loading the printer with the ink of claim 1 ; and

(h) printing onto the substrate using the ink in response to the digital data signals to form a printed image on the substrate.

21. A method of inkjet printing onto a substrate comprising, in any workable order, the steps of:

(e) providing an inkjet printer that is responsive to digital data signals;

(t) loading the printer with a substrate to be printed;

(g) loading the printer with the ink set of claim 19 ; and

(h) printing onto the substrate using the ink set in response to the digital data signals to form a printed image on the substrate.