Toner and image forming apparatus
To provide a toner, which contains: toner base particles each containing a binder resin and a colorant; and an external additive containing inorganic particles and fatty acid metal salt particles, wherein the inorganic particles contain at least hydrophobic silica particles, wherein a liberation ratio Ya of the hydrophobic silica particles from the toner is 1% by mass to 20% by mass, and wherein a libration ratio Yb of the fatty acid metal salt particles from the toner is 30% by mass to 90% by mass.
1. A toner, comprising:
toner base particles each comprising a binder resin and a colorant; and
an external additive comprising inorganic particles and fatty acid metal salt particles,
wherein the inorganic particles comprise at least hydrophobic silica particles,
wherein a liberation ratio Ya of the hydrophobic silica particles from the toner is 1% by mass to 20% by mass, and
wherein a libration ratio Yb of the fatty acid metal salt particles from the toner is 30% by mass to 90% by mass.
2. The toner according to claim 1 , wherein the libration ratio Ya of the hydrophobic silica particles is 2% by mass to 10% by mass, and the libration ratio Yb of the fatty acid metal salt particles is 45% by mass to 70% by mass.
3. The toner according to claim 1 , wherein a covering ratio of the toner base particle with the inorganic particles is 50% to 85%.
4. The toner according to claim 1 , wherein the fatty acid metal salt particles have the volume average particle diameter of greater than 0.65 μm but 10 μm or smaller.
5. The toner according to claim 1 , wherein an amount of the fatty acid metal salt particles is 0.05 parts by mass to 0.4 parts by mass, relative to 100 parts by mass of the toner base particles.
6. The toner according to claim 1 , wherein the fatty acid metal salt particles are zinc stearate particles.
7. The toner according to claim 1 , wherein the toner is obtained by externally adding the inorganic particles to the toner base particles, followed by externally adding the fatty acid metal salt particles to the toner base particles.
8. The toner according to claim 1 , wherein the binder resin comprises a non-crystalline resin and a crystalline resin.
9. The toner according to claim 1 , wherein the toner base particles are obtained by a method comprising:
dissolving or dispersing the binder resin, an active hydrogen group-containing compound, a binder resin precursor having a site reactive with the active hydrogen group-containing compound, a colorant, and a releasing agent in an organic solvent to prepare a solution or a dispersion liquid;
emulsifying the solution or the dispersion liquid in an aqueous medium to prepare an emulsion;
allowing the binder resin precursor and the active hydrogen group-containing compound to react in the emulsion; and
removing the organic solvent.