Alkylation process
The present invention provides an improved process for the catalytic conversion of a feedstock comprising an alkylatable aromatic compound and an alkylating agent to form a conversion product comprising the desired alkylaromatic compound by contacting said feedstock in at least partial liquid phase under catalytic conversion conditions with a catalyst composition comprising a porous crystalline material having a structure type of FAU, BEA* or MWW, or a mixture thereof, wherein the porous crystalline material has a Relative Activity measured at 220° C. as an RA 220 of at least 7.5 or measured at 180° C. as RA 180 of at least 2.5, allowing operation at lower reaction pressures, e.g., a reaction pressure of about 450 psig (3102 kPa) or less, and lower alkylating agent feed supply pressure of 450 psig (3102 kPa) or less.
1. In a process for catalytic conversion of a feedstock comprising at least one alkylatable aromatic compound comprising benzene and an alkylating agent comprising ethylene or propylene to form a conversion product comprising an alkylaromatic compound, the process comprising the step of contacting said feedstock in at least partial liquid phase under catalytic conversion conditions including a reactor outlet pressure and an alkylating agent feed supply pressure, with a catalyst composition comprising a porous crystalline material having a MWW structure selected from the group consisting of MCM-22, MCM-36, MCM-49, MCM-56, ITQ-1, ITQ-2, ITQ-30, PSH-3, SSZ-25, ERB-1, UZM-8, UZM-8HS and mixtures thereof, the improvement comprising the steps of:
(a) modifying said catalyst composition to have a Relative Activity measured as an RA 220 at 220° C. of 8.6 to 12.0 or RA 180 at 180° C. of from 3.5 to 6.0 by:
(i) increasing the zeolite content of said catalyst composition or steaming the catalyst composition to increase the Alpha Value, or
(ii) decreasing the zeolite content of said catalyst composition or steaming the catalyst composition to decrease the Alpha Value; and
(b) lowering said reactor pressure to about 370 psig (3102 kPa) or less or said alkylating agent feed supply pressure from about 370 psig (3102 kPa) or less, wherein said Relative Activity is the percent temperature rise in an adiabatic pipe reactor having one or more thermocouples divided by the percentage bed length based on the position of said thermocouples in said reactor.
2. The process of claim 1 , wherein said conversion conditions include said molar ratio of alkylatable aromatic compound to alkylating agent of from about 0.5:1 to about 10:1, and said feed weight hourly space velocity (WHSV) based on the alkylating agent of from about 0.1 to about 50 hr −1 .
3. The process of claim 1 , when said alkylatable aromatic compound comprises benzene, and said alkylating agent comprises ethylene, said alkylaromatic compound comprises ethylbenzene.
4. The process of claim 1 , when said alkylatable aromatic compound comprises benzene, and said alkylating agent comprises propylene, said alkylaromatic compound comprises cumene.