Blended fluoropolymer compositions and coatings for flexible substrates
Blended fluoropolymer compositions that, in one exemplary application, may be applied as a coating to a flexible substrate and, optionally, to a flexible substrate that has been previously coated with a primer or basecoat and/or a midcoat. In one embodiment, the composition is a blend of at least one low molecular weight polytetrafluoroethyelene (LPTFE) and at least one melt-processible fluoropolymer (MPF). In another embodiment, the composition includes a fluoropolymer base component including at least one fluoropolymer such as high molecular weight polytetrafluoroethylene (HPTFE), and additionally includes the LPTFE/MPF blended fluoropolymer composition. After being applied to the flexible substrate, optionally over a primer or basecoat and/or midcoat, and then cured, the present compositions form coatings that demonstrate improved abrasion resistance and/or improved release characteristics and/or increased translucency/transparency and/or improved impermeability. The present compositions may also be used to produce films having a high degree of clarity and impermeability. The present compositions in powder form may be melt or paste extruded to form articles with improved impermeability.
1. A coated flexible substrate, comprising:
a flexible substrate;
a coating on said flexible substrate, comprising:
at least one fluoropolymer including high molecular weight polytetrafluoroethylene (HPTFE) having a number average molecular weight (M n ) of at least 500,000 and present in an amount of between 70 wt. % and 98 wt. % based on the total solids weight of all fluoropolymers in said coating;
at least one low molecular weight polytetrafluoroethylene (LPTFE) having a number average molecular weight (M n ) of less than 500,000 and present in an amount of between 1 wt. % and 30 wt. % based on the total weight of all fluoropolymers in said coating; and
at least one melt-processible fluoropolymer present in an amount of between 1 wt. % and 30 wt. % based on the total weight of all fluoropolymers in said coating;
said at least one melt-processible fluoropolymer (MPF) comprises perfluoroalkoxy (PFA), said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount between 45 wt. % and 55 wt. % and said PFA is present in an amount of between 45 wt. % and 55 wt. % based on the total solids weight of said at least one LPTFE and said PFA; and
said at least one high molecular weight polytetrafluoroethylene (HPTFE) includes a modifying co-monomer in an amount less than 1 wt. % based on the weight of said high molecular weight polytetrafluoroethylene (HPTFE).
2. The coated flexible substrate of claim 1 , wherein said at least one low molecular weight polytetrafluoroethylene (LPTFE) is present in an amount of between 5 wt. % and 15 wt. %, and said at least one melt-processible fluoropolymer present in an amount of between 5 wt. % and 15 wt. %, based on the total weight of all fluoropolymers in said coating.
3. The coated flexible substrate of claim 1 , wherein said at least one high molecular weight polytetrafluoroethylene (HPTFE) is present in an amount of between 85 wt. % and 95 wt. %, and said at least one low molecular weight polytetrafluoroethylene (LPTFE) and said at least one melt-processible fluoropolymer (MPF) are together present in an amount of between 5 wt. % and 15 wt. %, based on the total solids weight of all fluoropolymers in said coating.
4. The coated flexible substrate of claim 3 , wherein said at least one high molecular weight polytetrafluoroethylene (HPTFE) is present in an amount of between 90 wt. % and 95 wt. %, and said at least one low molecular weight polytetrafluoroethylene (LPTFE) and said at least one melt-processible fluoropolymer (MPF) are together present in an amount of between 5 wt. % and 10 wt. %, based on the total solids weight of all fluoropolymers in said coating.
5. The coated flexible substrate of claim 1 , wherein said modifying co-monomer is perfluoropropylvinyl ether (PPVE).
6. The coated flexible substrate of claim 1 , wherein said modifying co-monomer is a perfluoroalkylvinyl ether.
7. The coated flexible substrate of claim 1 , wherein said coating has a contact angle of at least 110°.
8. The coated flexible substrate of claim 7 , wherein said coating has a contact angle of at least 120°.
9. The coated flexible substrate of claim 1 , wherein said coating has a measured gloss of at least 25% reflectance at 60°.
10. The coated flexible substrate of claim 1 , wherein said coating has a surface roughness (R a ) of less than 100 nm.
11. The coated flexible substrate of claim 1 , wherein said low molecular weight polytetrafluoroethylene (LPTFE) is obtained via emulsion polymerization without being subjected to agglomeration, thermal degradation, or irradiation.