Low application tempearature amorphous poly-α-olefin adhesive
View Patent ↗It has been discovered that amorphous polybutene copolymers that have a softening point of from about 70 to about 105° C. and viscosity of less than about 1,900 cP at 190° C. possesses desirable properties and may be used to make a low application temperature hot melt adhesive for disposable absorbent articles.
1. A hot melt adhesive comprising at least 45 wt %, based on the adhesive, of an amorphous polybutene copolymer having (a) greater than about 50 wt % of 1-butene monomer, (b) a softening point of from about 70 to about 105° C. and (c) a viscosity of less than about 1,900 cP at 190° C., and (d) a tan δ value greater than 30 at 140° C.
wherein the hot melt adhesive has a viscosity of less than about 6,000 cP at 150° C.
2. The hot melt adhesive of claim 1 wherein the amorphous polybutene copolymer further comprises propylene comonomer.
3. The hot melt adhesive of claim 1 further comprising a tackifier which has a softening point greater than or equal to 80° C.
4. The hot melt adhesive of claim 3 wherein the tackifier has a softening point greater than or equal to 100° C.
5. The hot melt adhesive of claim 3 wherein the tackifier is selected from the group consisting of C5 resins, petroleum distillates, hydrogenated hydrocarbons, C5/C9, polyterpenes, rosin, hydrogenated rosin, and rosin esters and mixtures thereof.
6. The hot melt adhesive of claim 1 further comprising a crystalline wax which has a melting point greater than 60° C.
7. The hot melt adhesive of claim 6 wherein the crystalline wax is selected from the group consisting of Fischer-Tropsch wax, petroleum based wax, conventional wax, natural-based wax, functionalized wax, polyolefin copolymers and mixtures thereof.
8. The hot melt adhesive of claim 1 which is essentially free of wax and/or plasticizer.
9. The hot melt adhesive of claim 1 which comprises greater than 60% of the 1-butene monomer.
10. The hot melt adhesive of claim 1 wherein the adhesive has a tensile peak value greater than 55 psi at 23° C. at a pulling rate of 12 in/min.
11. An article comprising the adhesive of claim 1 .
12. The article of claim 11 which is a personal care, health, medical, household or industrial product.
13. The article of claim 12 which is a diaper, training pants, feminine hygiene pad, meat pads and adult incontinence products.