Radiopaque enhanced cobalt alloy for stents
A stent is formed of at least a cobalt-based alloy. The cobalt-based alloy may include 10-35 weight % metal member selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof; 16-21 weight % chromium (Cr); 9-12 weight % molybdenum (Mo); 0-25 weight % nickel (Ni); and balance cobalt (Co). The cobalt-based alloy may be a thin outer shell of a hollow stent. The cobalt-based alloy may be used to form at least one of an inner core and an outer shell of a core-shell structure of a stent. The cobalt-based alloy may be used to form an end of a wire for forming a stent.
1. A medical device comprising:
a cobalt-based alloy comprising
10-35 weight % material selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof;
16-21 weight % chromium (Cr);
9-12 weight % molybdenum (Mo);
3-25 weight % nickel (Ni); and
balance cobalt (Co).
2. The medical device of claim 1 , wherein the cobalt-based alloy further comprises one or more of
0-3 weight % iron (Fe);
0-0.015 weight % boron (B);
0-0.15 weight % carbon (C);
0-1.5 weight % manganese (Mn);
0-0.04 weight % phosphorous (P);
0-1.0 weight % silicon (Si);
0-1 weight % titanium (Ti); and
0-0.03 weight % sulfur (S).
3. The medical device of claim 1 , wherein the cobalt-based alloy further comprises one or more of
about 0.010 weight % boron (B);
0-0.025 weight % carbon (C);
0-1.0 weight % iron (Fe);
0-0.15 weight % manganese (Mn);
0-0.015 weight % phosphorous (P);
0-0.15 weight % silicon (Si);
0-0.01 weight % sulfur (S); and
0-1 weight % titanium (Ti).
4. The medical device of claim 1 , wherein the cobalt-based alloy is formed of
about 24 weight % platinum (Pt);
about 20 weight % chromium (Cr);
about 10 weight % molybdenum (Mo);
about 15 weight % nickel (Ni); and
balance cobalt (Co).
5. The medical device of claim 1 , wherein the cobalt-based alloy is formed of
about 20.1 weight % platinum (Pt);
about 16.8 weight % chromium (Cr);
about 11.1 weight % molybdenum (Mo);
about 17.2 weight % nickel (Ni); and
balance cobalt (Co).
6. The medical device of claim 1 , wherein the cobalt-based alloy is formed of
about 0.015 weight % boron (B);
about 0.025 weight % carbon (C);
about 20 weight % chromium (Cr);
about 1 weight % iron (Fe);
about 0.15 weight % manganese (Mn);
about 10 weight % molybdenum (Mo);
about 12 weight % nickel (Ni);
about 0.015 weight % phosphorous (P);
about 24 weight % platinum (Pt);
about 0.15 weight % silicon (Si);
about 0.01 weight % sulfur (S);
about 0.01 weight % titanium (Ti); and
balance cobalt (Co).
7. The medical device of claim 1 , wherein the cobalt-based alloy forms at least one strut of the stent.
8. The medical device of claim 1 , wherein the stent comprises a core-shell structure having an outer shell substantially surrounding an inner core, and wherein one or more of the outer shell and the inner core is formed of the cobalt-based alloy.
9. The medical device of claim 1 , wherein the stent comprises a core-shell structure having an outer shell substantially surrounding an inner core, wherein one of the outer shell and the inner core is formed of the cobalt-based alloy and the other thereof is formed of a metal member.
10. The medical device of claim 9 , wherein the metal member is a metal selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof.
11. The medical device of claim 1 , wherein the stent comprises a core-shell structure having an outer shell substantially surrounding an inner core, and wherein the inner core is hollow and the outer shell is formed of the cobalt-based alloy having a thickness of about 0.0010 inches or less.
12. The medical device of claim 1 , wherein the stent comprises a core-shell structure having an outer shell substantially surrounding an inner core comprising Ta, wherein the outer shell comprises the cobalt-based alloy formed of
about 24 weight % platinum (Pt);
about 20 weight % chromium (Cr);
about 10 weight % molybdenum (Mo);
about 12 weight % nickel (Ni); and
balance cobalt (Co).
13. The medical device of claim 1 , wherein the stent comprises a core-shell structure having an outer shell substantially surrounding an inner core comprising Ta, wherein the outer shell comprises the cobalt-based alloy formed of
about 19.5 weight % platinum (Pt);
about 19 weight % chromium (Cr);
about 11 weight % molybdenum (Mo);
about 17 weight % nickel (Ni); and
balance cobalt (Co).
14. A medical device comprising:
a cobalt-based alloy comprising
10-35 weight % material selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof;
about 24 weight % platinum (Pt);
about 20 weight % chromium (Cr);
about 10 weight % molybdenum (Mo);
about 15 weight % nickel (Ni); and
balance cobalt (Co).
15. A medical device comprising:
a cobalt-based alloy comprising
10-35 weight % material selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof;
about 20.1 weight % platinum (Pt);
about 16.8 weight % chromium (Cr);
about 11.1 weight % molybdenum (Mo);
about 17.2 weight % nickel (Ni); and
balance cobalt (Co).
16. A medical device comprises a core-shell structure having an outer shell substantially surrounding an inner core comprising Ta, wherein the outer shell comprises
a cobalt-based alloy comprising
10-35 weight % material selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof;
about 19.5 weight % platinum (Pt);
about 19 weight % chromium (Cr);
about 11 weight % molybdenum (Mo);
about 17 weight % nickel (Ni); and
balance cobalt (Co).
17. A medical device comprising:
a cobalt-based alloy comprising
10-35 weight % material selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof;
about 0.015 weight % boron (B);
about 0.025 weight % carbon (C);
about 20 weight % chromium (Cr);
about 1 weight % iron (Fe);
about 0.15 weight % manganese (Mn);
about 10 weight % molybdenum (Mo);
about 12 weight % nickel (Ni);
about 0.015 weight % phosphorous (P);
about 24 weight % platinum (Pt);
about 0.15 weight % silicon (Si);
about 0.01 weight % sulfur (S);
about 0.01 weight % titanium (Ti); and
balance cobalt (Co).
18. A medical device comprises a core-shell structure having an outer shell substantially surrounding an inner core comprising Ta, wherein the outer shell comprises a cobalt-based alloy comprising
10-35 weight % material selected from the group consisting of platinum (Pt), gold (Au), iridium (Ir), osmium (Os), rhenium (Re), tungsten (W), palladium (Pd), tantalum (Ta), and combinations thereof;
about 24 weight % platinum (Pt);
about 20 weight % chromium (Cr);
about 10 weight % molybdenum (Mo);
about 12 weight % nickel (Ni); and
balance cobalt (Co).