Printing form precursor having elastomeric cap layer and a method of preparing a printing form from the precursor
View Patent ↗The invention pertains to a printing form precursor, a method of preparing a printing form from the precursor, and a process of preparing the precursor. The printing form precursor includes a photopolymerizable layer, an elastomeric layer having at least an elastomeric binder and particulate, and an actinic radiation opaque material on, adjacent, or disposed above the elastomeric layer opposite the photopolymerizable layer. The particulate is selected from specific material particles having an average diameter from 1 to 10 micron and a refractive index that is within 0.04 units of an index of refraction of the composition forming the elastomeric layer.
1. A printing form precursor comprising:
a) a layer of a photopolymerizable composition sensitive to actinic radiation, the composition comprising a binder, a monomer, and a photo initiator;
b) a layer of an elastomeric composition, that is or becomes sensitive to the actinic radiation, comprising at least an elastomeric binder, and particulate, the elastomeric composition having an index of refraction;
wherein the particulate is selected from polyamide, polymethylmethacrylate, feldspar, nepheline syenite, or glass particles, the particulate having an average diameter from 1 to 10 micron and an index of refraction that is ±0.04 of the index of refraction of the elastomeric composition; and
c) an actinic radiation opaque layer on, adjacent, or disposed above the elastomeric layer b) opposite the photopolymerizable layer a), that is capable of forming an in-situ mask.
2. The printing form precursor of claim 1 wherein the particulate has a particle size distribution in which 99.7% of the particles is within 1 to 10 micron.
3. The printing form precursor of claim 1 wherein less than 2% of the particulate has a particle size greater than 10 micron.
4. The printing form precursor of claim 1 wherein less than 0.5% of the particulate has a particle size greater than 10 micron.
5. The printing form precursor of claim 1 wherein the average diameter of the particulate is from 2 to 9 micron.
6. The printing form precursor of claim 1 wherein the average diameter of the particulate is from 5 to 8 micron.
7. The printing form precursor of claim 1 wherein the particulate is polyamide.
8. The printing form precursor of claim 1 wherein the particulate is polymethylmethacrylate.
9. The printing form precursor of claim 1 wherein the particulate is feldspar.
10. The printing form precursor of claim 1 wherein the particulate is nepheline syenite.
11. The printing form precursor of claim 1 wherein the glass particulate is soda lime glass.
12. The printing form precursor of claim 1 wherein the particulate is from 5 to 40% by weight of the elastomeric composition.
13. The printing form precursor of claim 1 wherein the particulate is from 15 to 35% by weight and the elastomeric binder is from 85 to 65% by weight of the elastomeric composition.
14. The printing form precursor of claim 1 wherein the elastomeric binder is selected from thermoplastic block-copolymers comprising elastomeric block and non-elastomeric block.
15. The printing form precursor of claim 1 wherein the elastomeric composition has a refractive index from 1.52 to 1.54, and the particulate has a refractive index from 1.48 to 1.58.
16. The printing form precursor of claim 1 wherein the binder in the elastomeric composition may be the same or different from the binder in the photopolymerizable composition.
17. The printing form precursor of claim 1 wherein the elastomeric layer has a thickness from 1 to 10 mil.