Accelerator/oxidant/proton source combinations for two part curable compositions

1. A two part curable composition comprising:

Part A: A proton source and one or more benzoyl thiourea or benzoyl thiourethane compounds within structures I or IA below:

wherein Z is O or N—R, where R is selected from hydrogen, alkyl, alkenyl, aryl, hydroxyalkyl, hydroxyalkenyl, alkylene (meth)acrylate, carbonyl, carboxyl, or sulfonato, and R′ taken together form a carbocyclic or hetero atom-containing ring, or R′ is a direct bond attaching to the phenyl ring; wherein X is optional, but when present X is halogen, alkyl, alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, alkoxy, amino, alkylene- or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, nitroso, sulfonate, hydroxyl or haloalkyl; and Y is —SO 2 NH—, —CONH—, —NH—, and —PO(NHCONHCSNH 2 )NH—; and n is 0 or 1 and m is 1 or 2, or

wherein R and R′ are independently selected from hydrogen, alkyl, alkenyl, aryl, hydroxyalkyl, hydroxyalkenyl, alkylene (meth)acrylate, carbonyl, carboxyl, or sulfonato, or R and R′ taken together form a carbocyclic or hetero atom-containing ring, or R′ is a direct bond attaching to the phenyl ring; wherein X is optional, but when present X is halogen, alkyl, alkenyl, cycloalkyl, hydroxyalkyl, hydroxyalkenyl, alkoxy, amino, alkylene- or alkenylene-ether, alkylene (meth)acrylate, carbonyl, carboxyl, sulfonate, hydroxyl or haloalkyl; and Y is —SO 2 NH—, —CONH—, —NH—, and —PO(NHCONHCSNH 2 )NH—; and n is 0 or 1 and m is 1 or 2; and

Part B: an oxidant,

wherein at least one of Part A or Part B comprises a (meth)acrylate component.

2. The composition of claim 1 , wherein the (meth)acrylate component is represented by H 2 C═CGCO 2 R 1 , wherein G may be hydrogen or alkyl groups having from 1 to about 4 carbon atoms, and R 1 may be selected from alkyl, cycloalkyl, alkenyl, cycloalkenyl, alkaryl, aralkyl or aryl groups having from 1 to about 16 carbon atoms, any of which may be optionally substituted or interrupted as the case may be with silane, silicon, oxygen, halogen, carbonyl, hydroxyl, ester, carboxylic acid, urea, urethane, carbonate, amine, amide, sulfur, sulfonate, and sulfone.

3. The composition of claim 1 , wherein the oxidant is a member selected from the group consisting of cumene hydroperoxide, para-menthane hydroperoxide, t-amyl hydroperoxide, 1,1,3,3-tetramethylbutyl hydroperoxide, t-butyl hydroperoxide, t-butyl perbenzoate, benzoyl peroxide, dibenzoyl peroxide, 1,3-bis(t-butylperoxyisopropyl)benzene, diacetyl peroxide, butyl 4,4-bis(t-butylperoxy)valerate, p-chlorobenzoyl peroxide, t-butyl cumyl peroxide, t-butyl perbenzoate, di-t-butyl peroxide, dicumyl peroxide, 2,5-dimethyl-2,5-di-t-butylperoxyhexane, 2,5-dimethyl-2,5-di-t-butyl-peroxyhex-3-yne, 4-methyl-2,2-di-t-butylperoxypentane and combinations thereof.

4. The composition of claim 1 , wherein the proton source is selected from the group consisting of water, alcohols, acids, and aldehydes.

5. The composition of claim 1 , wherein the proton source is an alcohol selected from the group consisting of hydroxy alkyl (meth)acrylates, alkanols, alkane di- and polyols.

6. The composition of claim 1 , wherein the proton source is an acid selected from the group consisting of acrylic acid and polymeric versions thereof, lactic acid, citric acid and combinations thereof.

7. The composition of claim 1 , wherein the proton source is an aldehyde selected from the group consisting of formaldeyde, acetaldehyde, ethyl aldehyde, propyl aldehydes, butyl aldehydes and benzaldehyde.

8. The composition of claim 1 , wherein the proton source is a silanol.

9. The composition of claim 1 , wherein the proton source is a silanol found on the surface of a glass substrate.

10. A bond formed between two mated substrates with the composition of claim 1 .

11. The composition of claim 1 , wherein the benzoyl thiourea or benzoyl thiourethane compound is selected from one or more of