Methods of forming modified thermoplastic structures for down-hole applications
A method of forming a modified thermoplastic structure for a down-hole application comprises forming a thermoplastic structure comprising at least one thermoplastic material formulated for crosslinking using an electron beam process. The thermoplastic structure is exposed to at least one electron beam to crosslink polymer chains of the thermoplastic structure. Other methods of forming a modified thermoplastic structure, and a down-hole tool are also described.
1. A method of forming a modified thermoplastic structure, comprising:
forming a material consisting of a thermoplastic powder consisting of thermoplastic particles selected from the group consisting of polyetherketone particles, polyetheretherketone particles, polyetherketoneketone particles, polyetherketoneetherketoneketone particles, polyphenylene sulfide particles, polyphenylsulfone particles, self-reinforced polyphenylene particles, and polyamideimide particles;
treating the material with at least one electron beam to crosslink at least a portion of polymer chains of at least a portion of the thermoplastic particles of the thermoplastic powder to form a modified material consisting of a modified thermoplastic powder;
combining the modified material with at least one crosslinking agent to form a further modified material, the at least one crosslinking agent formulated for crosslinking polymer chains of the modified thermoplastic powder upon exposure to at least one additional electron beam; and
forming the further modified material into a thermoplastic structure.
2. The method of claim 1 , wherein treating the material with at least one electron beam to crosslink at least a portion of the polymer chains of at least a portion of the thermoplastic particles comprises effectuating intra-particle crosslinking of the thermoplastic particles without substantially effectuating interparticle crosslinking of the thermoplastic particles.
3. The method of claim 1 , wherein treating the material with at least one electron beam comprises exposing the material to the at least one electron beam in an inert atmosphere.
4. The method of claim 1 , further comprising exposing the material to an oxygen containing atmosphere prior to treating the material with the at least one electron beam.
5. The method of claim 1 , wherein combining the modified material with at least one crosslinking agent comprises combining the modified material with the crosslinking agent at a ratio within a range of from about 0.05 parts to about 50 parts of the crosslinking agent per 100 parts of the modified material.
6. The method of claim 1 , further comprising subjecting the thermoplastic structure to an electron beam process to crosslink polymer chains of at least a portion of the thermoplastic structure.
7. The method of claim 1 , wherein treating the material with at least one electron beam to crosslink at least a portion of the polymer chains of at least a portion of the thermoplastic particles of the thermoplastic powder to form a modified material comprises converting at least a portion of thermoplastic material of one or more of the thermoplastic particles into a thermoset material.
8. The method of claim 7 , wherein converting at least a portion of the thermoplastic material of one or more of the thermoplastic particles into a thermoset material comprises completely converting at least some of the thermoplastic particles into thermoset particles.