Metal nanowires, nanomesh, and a method of fabrication
The present invention relates to a method of forming copper nanowires with a metallic coating. In a preferred embodiment, the metallic coating is copper. Due to the metal coating, the nanowires become magnetically guidable and chemically stable. As such, the nanowires can be used to form nanomesh. Further, the nanowire and nanomesh of the present invention can be used as transparent electrodes that are used in TV, PC, touch-control, and solar industries.
1. A method of making a plurality of metal-coated copper nanowires, comprising:
preparing an aqueous solution of sodium hydroxide (NaOH), copper ions, and a metal-containing compound;
sequentially adding ethylenediamine (EDA) to the aqueous solution;
sequentially adding hydrazine to the aqueous solution;
mixing the aqueous solution; and
heating the aqueous solution to produce a plurality of metal-coated copper nanowires.
2. The method according to claim 1 , wherein an inorganic or organic salt containing copper ions, cupric nitrate (Cu(NO 3 ) 2 ), or copper chloride are a source of the copper ions.
3. The method according to claim 1 , wherein the metal-containing compound comprises a metal selected from Gold (Au), Silver (Ag), Platinum (Pt), Palladium (Pd), Rhodium (Rh), Ruthenium (Ru), Cobalt (Co), or nickel (Ni).
4. The method according to claim 1 , wherein the metal-containing compound is a metal salt.
5. The method according to claim 1 , wherein the metal-containing compound is selected from an inorganic or organic salt containing nickel ions, nickel nitrate (Ni(NO 3 ) 2 ), or nickel chloride.
6. The method according to claim 1 , wherein the heating occurs at a temperature of about 25° C. to about 100° C. for about 15 minutes to about 15 hours.
7. The method according to claim 6 , wherein the temperature is about 60° C. to about 80° C.
8. The method according to claim 1 , wherein the sodium hydroxide (NaOH) has a concentration of about 3.5 M to 15.0 M and a volume of about 20 to about 30 mL.
9. The method according to claim 1 , wherein the copper ions have a concentration of about 0.10 M and a volume of about 0.1 to about 2.0 mL.
10. The method according to claim 1 , wherein the ethylenediamine (EDA) is added at a volume of about 0.050 mL to about 2.0 mL, and the hydrazine is sequentially added at a volume of about 0.020 mL to about 1.0 mL.
11. The method according to claim 1 , wherein the heating the aqueous solution is in a reactor and the reactor is in a water bath or any heating devices.
12. The method according to claim 11 , wherein the reactor is composed of glass.
13. The method according to claim 11 , wherein the reactor is composed of plastic or metals.
14. The method according to claim 1 , wherein the method is a continuous process.
15. The method according to claim 1 , wherein the method is a batch process.
16. The method according to claim 1 , wherein the copper ions are cupric nitrate (Cu(NO 3 ) 2 ) and the metal-containing compound comprises nickel nitrate Ni(NO 3 ) 2 ,
the sodium hydroxide (NaOH) has a concentration of about 7.0 M and a volume of about 30 mL;
the cupric nitrate (Cu(NO 3 ) 2 ) has a concentration of about 0.10 M and a volume of about 0.1 to about 1.0 mL; and
the nickel nitrate Ni(NO 3 ) 2 has a concentration of about 0.5 M and a volume of 0.07 mL to about 0.30 mL.
17. The method according to claim 1 , wherein the copper ions are cupric nitrate (Cu(NO 3 ) 2 ), and wherein the cupric nitrate (Cu(NO 3 ) 2 ) has a concentration of about 0.5 M and a volume of about 0.07 to about 0.20 mL.
18. The method according to claim 1 , wherein the volume of ethylenediamine (EDA) added is about 0.15 to 0.50 mL; and the volume of hydrazine added is about 0.025 mL to about 0.20 mL.
19. The method according to claim 1 , wherein the heating is to a temperature of about 80° C. for about 1 hour.
20. The method according to claim 1 , further comprising:
removing the plurality of metal coated copper nanowires; and
cooling the plurality of metal coated copper nanowires in air.