Fluorine rubber composition and bladder for tire production
View Patent ↗A fluorine rubber composition that provides high tensile strength and high elongation after vulcanization mutually compatible and from which favorable mechanical characteristics are obtained even in a high-temperature environment; and a bladder for tire production, which is manufactured using the same are provided. The fluorine rubber composition includes a rubber component containing a fluorine rubber and carbon black, wherein the carbon black has a specific surface area by nitrogen adsorption (N2SA) of 25 m2/g or more and not more than 180 m2/g and a dibutyl phthalate (DBP) absorption amount of 60 mL/100 g or more and not more than 180 mL/100 g; and in a kneading step (A) of compounding the carbon black in the rubber component, an average shear rate of a rotor surface of a kneading machine is 100 (1/sec) or more, and a kneading maximum temperature Tm is 120° C. or higher and not higher than 200° C.
1. A fluorine rubber composition comprising a rubber component comprising:
a fluorine rubber;
carbon black; and
a vulcanization system compounding agent containing a co-crosslinking agent,
wherein the carbon black has a specific surface area by nitrogen adsorption (N 2 SA) of 25 m 2 /g or more and not more than 180 m 2 /g and a dibutyl phthalate (DBP) absorption amount of 60 mL/100 g or more and not more than 180 mL/100 g;
the fluorine rubber is at least one member selected among (A) a copolymer of tetrafluoroethylene/perfluoroalkyl vinyl ether, (B) a copolymer of tetrafluoroethylene/propylene, and (C) a copolymer made of (i) at least one monomer selected among tetrafluoroethylene, hexafluoropropene, pentafluoropropene, trifluoroethylene, chlorotrifluoroethylene, vinyl fluoride, perfluoroalkyl vinyl ether and propylene, and (ii) vinylidene fluoride; and
in a kneading step of compounding the carbon black in the rubber component, an average shear rate of a rotor tip point of a kneading machine is 100 (1/sec) or more, and a kneading maximum temperature T m is 120° C. or higher and not higher than 200° C.,
wherein the elongation at break at 25° C. of the fluorine rubber composition after vulcanization is 400% or more and not more than 800%, and
wherein a compounding amount of the co-crosslinking agent is 0.1 to 2.5 parts by mass based on 100 parts by mass of the rubber component.
2. The fluorine rubber composition according to claim 1 , wherein a compounding amount of the carbon black is 10 parts by mass or more and not more than 50 parts by mass based on 100 parts by mass of the rubber component.
3. The fluorine rubber composition according to claim 1 , wherein
the vulcanization system compounding agent contains an organic peroxide and a co-crosslinking agent; and a compounding amount of the organic peroxide component is 0.1 parts by mass or more and not more than 3.0 parts by mass based on 100 parts by mass of the rubber component.
4. The fluorine rubber composition according to claim 3 , wherein the organic peroxide is a dialkyl peroxide.
5. The fluorine rubber composition according to claim 3 , wherein the co-crosslinking agent is triallyl isocyanurate.
6. The fluorine rubber composition according to claim 1 , further comprising an alkylamine in an amount of 0.1 parts by mass or more and not more than 5.0 parts by mass based on 100 parts by mass of the rubber component.
7. A bladder for tire production, which is manufactured using the fluorine rubber composition according to claim 1 .