IP Library Granted Patent US 8,802,889
Granted Patent B2
US 8,802,889 · App. 13/820,323 · Granted Aug 12, 2014

Process for production of allyl acetate

View Patent ↗
Loading inventors, assignments & file history…
Monitor This Case
Get email alerts when status or documents change.
Order Certified Copies
Most orders are placed with the USPTO same day — all within 24 business hours.
Order via The Patent Place →
Pre-filled with this patent's details
Quick Facts
Patent No.
US 8,802,889
App. No.
13/820,323
Granted
Aug 12, 2014
Kind
B2
Abstract

A process for production of allyl acetate includes steps of reacting acetic acid 3 , oxygen 1 and propylene 2 in the presence of a catalyst in an oxidation reactor 5 to form allyl acetate and water; separating the unreacted acetic acid by a distillation column 9 ; and recovering an acetic acid-containing liquid which contains acetic acid and returning the acetic acid-containing liquid to the oxidation reactor 5 via an acetic acid-water evaporator 4 , the process further including a heating step of heating a process liquid which contains the acetic acid-containing liquid to a temperature of 80 to 250° C. by a heater.

Claims (14)

1. A process for producing allyl acetate, comprising:

reacting acetic acid, oxygen, and propylene in the presence of a catalyst in a reactor to produce allyl acetate and water;

separating the unreacted acetic acid by a distillation column;

recovering an acetic acid-containing liquid which contains acetic acid and returning the acetic acid-containing liquid to the reactor via an acetic acid-water evaporator; and

heating a process liquid which contains the acetic acid-containing liquid to a temperature of 80 to 250° C. by a heater to polymerize unsaturated compounds,

wherein the process liquid is the bottom liquid of the acetic acid-water evaporator.

2. The process for producing allyl acetate according to claim 1 , wherein an evaporator is used as the heater.

3. The process for producing allyl acetate according to claim 1 , wherein the process liquid after the heating is returned to the distillation column.

4. The process for producing allyl acetate according to claim 1 , further comprising:

hydrolyzing, before the separating, the allyl acetate; and

supplying an acetic acid-containing liquid containing the acetic acid formed by the hydrolysis to the distillation column for the separating.

5. The process for production of allyl acetate according to claim 4 , wherein the distillation column separates acetic acid formed by the hydrolysis.

6. The process for production of allyl acetate according to claim 1 , wherein a heating temperature in the heater is from 100° C. to 150° C.

7. The process for production of allyl acetate according to claim 1 , wherein a residence time in the heater is 5.0 minutes or more.

Assignments (4)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 18, 2025
From: RESONAC CORPORATION
To: CRASUS CHEMICAL INC.
Reel/Frame 072044/0367 →
CHANGE OF ADDRESS Recorded Feb 14, 2024
From: RESONAC CORPORATION
To: RESONAC CORPORATION
Reel/Frame 066599/0037 →
CHANGE OF NAME Recorded Jun 23, 2023
From: SHOWA DENKO K.K.
To: RESONAC CORPORATION
Reel/Frame 064082/0513 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 1, 2013
From: OGUCHI, WATARU
To: SHOWA DENKO K.K.
Reel/Frame 029907/0703 →