Thermally stable compositions containing resin-linear organosiloxane block copolymers
View Patent ↗Solid compositions of organosiloxane block copolymers are disclosed having a tensile strength greater than 1.0 MPa and a % elongation at break greater than 40%. The organosiloxane block copolymers comprise: 40 to 90 mole percent disiloxy units of the formula [R 1 2 SiO 2/2 ] 10 to 60 mole percent trisiloxy units of the formula [R 2 SiO 3/2 ] 0.5 to 35 mole percent silanol groups [≡SiOH] where R 1 is independently a C 1 to C 30 hydrocarbyl, R 2 is independently a C 1 to C 20 hydrocarbyl, wherein; the disiloxy units [R 1 2 SiO 2/2 ] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R 1 2 SiO 2/2 ] per linear block, the trisiloxy units [R 2 SiO 3/2 ] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, and at least 30% of the non-linear blocks are crosslinked with each other, each linear block is linked to at least one non-linear block, and the organosiloxane block copolymer has a molecular weight (M w ) of at least 20,000 g/mole.
1. A solid composition comprising an organosiloxane block copolymer having
40 to 90 mole percent disiloxy units of the formula [R 1 2 SiO 2/2 ]
10 to 60 mole percent trisiloxy units of the formula [R 2 SiO 3/2 ]
0.5 to 25 mole percent silanol groups [≡SiOH]
where R 1 is independently a C 1 to C 30 hydrocarbyl,
R 2 is independently a C 1 to C 20 hydrocarbyl,
wherein;
the disiloxy units [R 1 2 SiO 2/2 ] are arranged in linear blocks having an average of from 10 to 400 disiloxy units [R 1 2 SiO 2/2 ] per linear block,
the trisiloxy units [R 2 SiO 3/2 ] are arranged in non-linear blocks having a molecular weight of at least 500 g/mol, at least 30% of the non-linear blocks are crosslinked with each other,
and are predominately aggregated together in nano-domains,
each linear block is linked to at least one non-linear block,
the organosiloxane block copolymer has a molecular weight of at least 20,000 g/mole, and the solid composition has a tensile strength greater than 1.0 MPa and an % elongation at break greater than 40%.
2. The solid composition of claim 1 wherein the organosiloxane block copolymer contains at least 30 weight percent disiloxy units.
3. The solid composition of claim 1 wherein the disiloxy units have the formula [(CH 3 ) 2 SiO 2/2 ].
4. The solid composition of claim 1 wherein the disiloxy units have the formula [(CH 3 )(C 6 H 5 )SiO 2/2 ].
5. The solid composition of claim 1 wherein R 2 is phenyl.
6. The solid composition of claim 1 wherein the tensile strength of the composition remains within 20% of the original value upon heat aging the composition at 200° C. for 1000 hours.
7. The solid composition of claim 1 wherein the elongation at break of the composition is at least 10% after heat aging the composition at 200° C. for 1000 hours.
8. The solid composition of claim 1 wherein the coating composition has a melt flow temperature ranging from 25° C. to 200° C.
9. The solid composition of claim 1 wherein the composition has a storage modulus (G′) at 25° C. ranging from 0.01 MPa to 500 MPa and a loss modulus (G″) at 25° C. ranging from 0.001 MPa to 250 MPa.
10. The solid composition of claim 9 wherein the composition has a storage modulus (G′) at 120° C. ranging from 10 Pa to 500,000 Pa and a loss modulus (G″) at 120° C. ranging from 10 Pa to 500,000 Pa.
11. The solid composition of claim 9 wherein the composition has a storage modulus (G′) at 200° C. ranging from 10 Pa to 100,000 Pa and a loss modulus (G″) at 200° C. ranging from 5 Pa to 80,000 Pa.
12. The solid composition of claim 1 wherein the solid composition has an optical clarity of greater than 95% light transmittance.
13. The solid composition of claim 1 having a % elongation at break from about 40% to about 420%.
14. The solid composition of claim 1 having a % elongation at break from about 100% to about 420%.
15. The solid composition of claim 1 having a % elongation at break from about 200% to about 420%.
16. The solid composition of claim 1 having a % elongation at break from about 40% to about 420%.
17. The solid composition of claim 1 having a tensile strength from about 1 MPa to about 9 MPa.
18. The solid composition of claim 1 having a tensile strength from about 1 MPa to about 5 MPa.
19. The solid composition of claim 1 having a % elongation at break from about 40% to about 110% after 1000 hours at 200° C.
20. The solid composition of claim 1 having a tensile strength from about 1 MPa to about 9 MPa after 1000 hours at 200° C.