IP Library Granted Patent US 9,404,005
Granted Patent B2
US 9,404,005 · App. 13/822,245 · Granted Aug 2, 2016

Recyclable thermoplastic insulation with improved breakdown strength

Inventors: Simon Sutton (Egham, GB); Theo E. Geussens (Samstagern, CH); Alun Vaughan (Winchester, GB); Gary Stevens (Surrey, GB)
Assignees: Dow Global Technologies LLC; Dow Chemical Company Limited; University of Southampton; GnoSys Global Ltd.
C09D123/06C08L23/06H01B3/307C08L2205/02
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Quick Facts
Patent No.
US 9,404,005
App. No.
13/822,245
Granted
Aug 2, 2016
Kind
B2
Abstract

The disclosure provides a process for producing a material with improved breakdown strength. The process includes heating a polymeric composition composed of a low density polyethylene (LDPE) and a minority amount of a high density polyethylene (HDPE). The polymeric composition is heated to at least the melting temperature of the HDPE. The process includes control-cooling the heated polymeric composition at a cooling rate from 0.1° C./min to 20° C./min, and forming a polymeric composition. The control-cooled polymeric composition has a unique morphology which improves breakdown strength. Also provided is a coated conductor with an insulating layer composed of the polymeric composition with the unique morphology. The insulating layer exhibits improved breakdown strength.

Claims (13)

1. A process comprising:

heating a polymeric composition consisting of (i) a low density polyethylene having a melting temperature of at least 105° C. to 125° C. (LDPE) (ii) a minority amount of a high density polyethylene having a melting temperature of at least 130° C. to 134° C. (HDPE), and (iii) optional antioxidant, to at least the melting temperature of the HDPE;

control-cooling the heated polymeric composition at a cooling rate from 0.1° C./min to 10° C./min; and

forming a polymeric composition having a space-filling array of HDPE lamellae, which are separated by the LDPE, the polymeric composition having an AC breakdown strength greater than 170 kV/mm as measured on 85 micrometer thin films in accordance with ASTM D 149.

2. The process of claim 1 comprising:

melt blending from about 5 wt % to about 35 wt % HDPE and from about 95 wt % to about 65 wt % of the LDPE, and

forming the polymeric composition.

3. The process of claim 1 comprising heating the polymeric composition to at least 130° C.; and control-cooling from 130° C. to 90° C.

4. The process of claim 1 comprising heating the polymeric composition to at least 130° C.; and

control-cooling the heated polymeric composition at a rate from 0.1° C./min to 10° C./min from 130° C. to 90° C.

5. The process of claim 1 comprising heating the polymeric composition to at least 130° C.;

control-cooling from 130° C. to 90° C.; and

quenching when the temperature of the heated polymeric composition is less than 105° C.

Assignments (7)
CHANGE OF NAME Recorded Oct 10, 2024
From: GNOSYS GLOBAL LTD
To: KINECTRICS UK LIMITED
Reel/Frame 068859/0334 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: GEUSSENS, THEO E.
To: DOW EUROPE GMBH
Reel/Frame 039015/0028 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: DOW EUROPE GMBH
To: THE DOW CHEMICAL COMPANY
Reel/Frame 039015/0071 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: THE DOW CHEMICAL COMPANY
To: DOW GLOBAL TECHNOLOGIES LLC
Reel/Frame 039015/0114 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: SUTTON, SIMON
To: DOW CHEMICAL COMPANY LIMITED
Reel/Frame 039015/0261 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: VAUGHAN, ALUN
To: UNIVERSITY OF SOUTHAMPTON
Reel/Frame 039016/0801 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jun 27, 2016
From: STEVENS, GARY
To: GNOSYS GLOBAL LTD.
Reel/Frame 039016/0854 →
Continuity (2)
Provisional Application 61388416 · Sep 30, 2010
Related Publication 20130175068A1 · Jul 11, 2013