Systems and Methods for Hydrothermal Conversion of Biomass
Systems and methods are provided for synthesizing low nitrogen concentration organic liquids from biomass, such as algae, the organic liquids being suitable for refining into fuels and other chemicals. The biomass together with a solvent that is immiscible with water at room temperature are subjected to a subcritical hydrothermal treatment to disrupt cell structure and transform the biomass into a gas phase, a bio-oil phase, an aqueous phase and a solid phase. The aqueous phase contains most of the nitrogen. The resulting multi-phasic mixture can be separated into four phases, including an aqueous phase and the organic liquid which consists of bio-oil dissolved in the solvent. Refined organic liquid can be recycled into the hydrothermal treatment as the solvent. The subcritical hydrothermal treatment can be performed at a generally low temperature and followed by a second hydrothermal treatment at a higher temperature.
1 . A method comprising:
a first hydrothermal treatment comprising treating together an aqueous suspension of a biomass and a first organic solvent, the first organic solvent being immiscible with water at room temperature, under a first subcritical hydrothermal condition comprising a first treatment temperature of between about 150° C. to about 350° C. and a pressure of between about 500 psi to about 3000 psi to produce a first multi-phasic mixture including an organic phase and an aqueous phase; and
separating the organic phase from the aqueous phase.
2 . The method of claim 1 wherein the first organic solvent comprises a hydrocarbon.
3 . The method of claim 1 wherein the aqueous suspension of the biomass includes between about 5% to about 30% of the biomass by weight.
4 . The method of claim 1 wherein the biomass comprises algae.
5 . The method of claim 1 wherein the volume ratio of water to the first organic solvent used in the subcritical treating step is between about 1:1 to about 10:1.
6 . The method of claim 1 wherein the biomass has a C:N less than about 10.
7 . The method of claim 1 wherein the organic phase, after the separation step, has a C:N of greater than about 40.
8 . The method of claim 1 further comprising recovering carbon from the aqueous phase produced by the separation step.
9 . The method of claim 8 further comprising providing the aqueous phase produced by the separation step to a digester to generate biogas.
10 . The method of claim 9 further comprising steam methane reforming of the biogas to convert the methane fraction thereof to hydrogen and carbon dioxide.
11 . The method of claim 9 further comprising steam gasification of the biogas to convert the methane fraction thereof to syngas.
12 . The method of claim 11 further comprising processing the syngas to produce a liquid hydrocarbon.
13 . The method of claim 8 wherein recovering carbon from the aqueous phase includes producing carbon dioxide.
14 . The method of claim 13 wherein the carbon dioxide is used to cultivate algae.
15 . The method of claim 13 wherein the carbon dioxide is fed into the first hydrothermal treatment.
16 . The method of claim 1 further comprising adding a catalyst to the first hydrothermal treatment.
17 . The method of claim 1 further comprising producing the aqueous suspension of the biomass before the first hydrothermal treatment.
18 . The method of claim 17 wherein producing the aqueous suspension of the biomass includes cultivating algae and dewatering the algae.
19 . The method of claim 1 further comprising converting the organic phase to a fuel.
20 . The method of claim 19 further comprising feeding some of the fuel back into the first hydrothermal treatment as at least a portion of the first organic solvent.
21 . The method of claim 1 wherein the first temperature is no more than about 200° C.
22 . The method of claim 21 wherein
the first multi-phasic mixture further includes a solid phase,
the separation step further comprises separating the solid phase from the organic and aqueous phases, and
the method further comprises
a second hydrothermal treatment comprising treating the solid phase under a second hydrothermal condition comprising a second treatment temperature above the first treatment temperature and a pressure of about 200 psi to about 3000 psi to produce a second multi-phasic mixture of an organic phase and an aqueous phase, and
separating the organic phase from the aqueous phase of the second multi-phasic mixture.
23 . The method of claim 22 further comprising converting the organic phases recovered from separating the first and second multi-phasic mixtures to a fuel.
24 . The method of claim 22 wherein the second hydrothermal treatment further includes treating the solids together with a second solvent.
25 . The method of claim 22 further comprising recovering carbon from the aqueous phase separated from the second multi-phasic mixture.
26 . The method of claim 22 wherein the second hydrothermal treatment comprises a second subcritical hydrothermal treatment.
27 . The method of claim 22 wherein the second hydrothermal treatment comprises a supercritical hydrothermal treatment.
28 . The method of claim 22 wherein carbon recovered from either aqueous phase is fed into the second hydrothermal treatment as carbon dioxide.
29 . A product consisting of the organic phase produced by the process of claim 4 .
30 . The product of claim 29 wherein the algae consists essentially of microalgae.
31 . A product consisting of the organic phase produced by the process of claim 22 , wherein the biomass comprises algae.
32 . The method of claim 1 wherein the first hydrothermal treatment is accomplished in a continuous steady-state reactor.