Aqueous pigment dispersions and inkjet inks
View Patent ↗The present disclosure pertains to an aqueous pigment dispersion containing a pigment as colorant, a polymeric dispersant and a hydroxyl-substituted amino acid. The present disclosure further pertains to an ink containing an aqueous vehicle and the aqueous pigment dispersion, and ink sets with at least one of the inks containing the pigment dispersion.
1. An aqueous pigment dispersion comprising a colorant and a hydroxyl-substituted amino acid or salt thereof as a viscosity modifier, wherein said colorant is dispersed with a polyurethane dispersant, and said hydroxyl-substituted amino acid has a structure of Formula I,
Z 1 is H or (CH 2 ) k OH; k is 1-6;
Z 2 is (CH 2 ) m OH; m is 1-5;
Z 3 is H or (CH 2 ) n OH; n is 1-5;
Z 4 is H or (CH 2 ) p OH; p is 1-5; and
wherein there are at least two hydroxyl alkyl substitutents on said amino acid.
2. The aqueous pigment dispersion of claim 1 , wherein the amount of the hydroxy-substituted amino acid is 0.01 to 2.0 weight percent of the aqueous pigment dispersion.
3. The aqueous pigment dispersion of claim 1 , wherein the amount of the hydroxyl-substituted amino acid is 0.02 to 1.0 weight percent of the aqueous pigment dispersion.
4. The aqueous pigment dispersion of claim 1 , wherein said hydroxyl-substituted amino acid is bicine which corresponds to Structure (I), wherein Z 1 is (CH 2 ) 2 OH, Z 2 is (CH 2 )OH, and Z 3 and Z 4 are H.
5. The aqueous pigment dispersion of claim 1 , wherein said hydroxyl-substituted amino acid is tricine which corresponds to Structure (I), wherein Z 1 is H, and Z 2 , Z 3 and Z 4 are (CH 2 )OH.
6. The aqueous pigment dispersion of claim 1 , wherein the colorant is selected from the group consisting of pigments, disperse dyes and mixtures thereof.
7. The aqueous pigment dispersion of claim 1 , wherein the amount of the colorant is from 5 to 30 weight percent of said aqueous pigment dispersion.
8. The aqueous pigment dispersion of claim 1 having a viscosity of less than the viscosity of a similar aqueous pigment dispersion without any hydroxyl-substituted amino acid.
9. The aqueous pigment dispersion of claim 1 , wherein the pH of said aqueous pigment dispersion is from 6 to 9.
10. An inkjet ink comprising an aqueous vehicle, an aqueous pigment dispersion comprising a colorant and a hydroxyl-substituted amino acid or salt thereof as a viscosity modifier; wherein said colorant is dispersed with a polyurethane dispersant, and said hydroxy-substituted amino acid has a structure of Formula I,
Z 1 is H or (CH 2 ) k OH; k is 1-6;
Z 2 is (CH 2 ) m OH; m is 1-5;
Z 3 is H or (CH 2 ) n OH; n is 1-5;
Z 4 is H or (CH 2 ) p OH; p is 1-5; and
wherein there are at least two hydroxyl alkyl substitutents on said amino acid.
11. The inkjet ink of claim 10 , wherein said polyurethane dispersant is substituted with crosslinkable moieties selected from the group consisting of acetoacetoxy, acid, amine, epoxy, hydroxyl, blocked isocyanates and mixtures thereof.
12. The inkjet ink of claim 11 , wherein said polyurethane dispersant substituted with crosslinkable moieties is reacted with a crosslinking agent selected from the group consisting of acetoacetoxy, acid, amine, anhydride, epoxy, hydroxyl, isocyanates, blocked isocyanates and mixtures thereof.
13. The inkjet ink of claim 10 , wherein said hydroxyl-substituted amino acid is bicine which corresponds to Structure (I), wherein Z 1 is (CH 2 ) 2 OH, Z 2 is (CH 2 )OH, and Z 3 and Z 4 are H.
14. The inkjet ink of claim 10 , wherein said hydroxyl-substituted amino acid is tricine which corresponds to Structure (I), wherein Z 1 is H, and Z 2 , Z 3 and Z 4 are (CH 2 )OH.
15. The inkjet ink of claim 10 , wherein said colorant is selected from the group consisting of pigments, disperse dyes and mixtures thereof.
16. An inkjet ink set comprising at least three differently colored inks, at least one of which is an ink as set forth in claim 10 .
17. The inkjet ink set of claim 16 , wherein the ink set comprises at least three differently colored inks, at least one of which is a yellow ink, at least one of which is a magenta ink, and at least one of which is a cyan ink.
18. The inkjet ink set of claim 17 , further comprising a black ink.
19. The aqueous pigment dispersion of claim 1 , wherein said polyurethane dispersant is crosslinked.
20. The inkjet ink of claim 10 , wherein said polyurethane dispersant is crosslinked.