Wave-length conversion inorganic member, and method for manufacturing the same
A wave-length conversion inorganic member can includes a base body and an inorganic particle layer on the base body. The inorganic particle layer can include particles of an inorganic wave-length conversion substance which is configured to absorb light of a first wave-length and to emit light of a second wave-length different from the first wave-length. The inorganic particle layer can include an agglomerate of a plurality of the particles. Each of the plurality of the particles are in contact with at least one of the other particles or the base body. A cover layer comprises an inorganic material, and the cover layer continuously covers a surface of the base body and surfaces of the particles. The inorganic particle layer has an interstice enclosed by the particles, or by the particles and one of the base body and the cover layer.
1. A wave-length conversion inorganic member comprising:
a base body; and
an inorganic particle layer on the base body, the inorganic particle layer including particles of an inorganic wave-length conversion substance which is configured to absorb light of a first wave-length and to emit light of a second wave-length different from the first wave-length,
the inorganic particle layer comprising
an agglomerate of the particles, wherein each of the particles are in contact with at least one of the other particles or the base body; and
a cover layer comprising an inorganic material, the cover layer continuously covering a surface of the base body and surfaces of the particles,
the inorganic particle layer having an interstice enclosed by the particles, or by the particles and one of the base body and the cover layer, and
wherein the base body comprises an inorganic wave-length conversion substance which absorbs the light of the first wave-length and emits light of a third wave-length different from the first wave-length and the second wave-length.
2. The wave-length conversion inorganic member according to claim 1 ,
wherein the inorganic particle layer has a plurality of interstices, and has a density of 1% to 50%.
3. The wave-length conversion inorganic member according to claim 1 ,
wherein the particles of the wave-length conversion substance have an average particle size of 0.1 μm to 100 μm, and
wherein the cover layer has an average thickness of 10 nm to 50 μm.
4. The wave-length conversion inorganic member according to claim 1 ,
wherein the inorganic particle layer has a concave and convex surface formed by variations in particle sizes of the particles of the wave-length conversion substance.
5. The wave-length conversion inorganic member according to claim 1 ,
wherein the cover layer is formed by atomic layer deposition.
6. The wave-length conversion inorganic member according to claim 1 ,
wherein the cover layer contains at least one compound selected from the group consisting of Al 2 O 3 , SiO 2 , ZrO 2 , HfO 2 , TiO 2 , ZnO, Ta 2 O 5 , Nb 2 O 5 , In 2 O 3 , SnO 2 , TiN, and AlN.
7. The wave-length conversion inorganic member according to claim 1 ,
wherein the wave-length conversion substance contains at least one compound selected from the group consisting of sulfide phosphor, halogen-silicate phosphor, nitride phosphor, and oxynitride phosphor.
8. A wave-length conversion inorganic member according to claim 1 ,
wherein each of the particles of the wave-length conversion substance is bonded to at least one of the other particles or the base body by an inorganic binder.
9. A method for manufacturing a wave-length conversion inorganic member, said method comprising:
an inorganic particle layer forming process for forming on a base body an agglomerate including particles of an inorganic wave-length conversion substance which absorbs light of a first wave-length, and emits light of a second wave-length different from the first wave-length; and
a cover-layer forming process for forming a cover layer comprising an inorganic material which continuously covers a surface of the base body and surfaces of the particles, and
wherein the base body comprises an inorganic wave-length conversion substance which absorbs the light of the first wave-length and emits light of a third wave-length different from the first wave-length and the second wave-length.
10. The method according to claim 9 ,
wherein the cover layer forming process comprises forming the cover layer by atomic layer deposition.