IP Library Granted Patent US 9,242,231
Granted Patent B2
US 9,242,231 · App. 13/855,258 · Granted Jan 26, 2016

Metal nanoparticle deposited inorganic nanostructure hybrids, uses thereof and processes for their preparation

Inventors: Reshef Tenne (Rehovot, IL); Yulia Tsverin (Rehovot, IL); Uwe Burghaus (Fargo, ND); Mallikharjuna Rao Komarneni (Fargo, ND)
Assignees: YEDA RESEARCH AND DEVELOPMENT CO., LTD.; NDSU RESEARCH FOUNDATION
B01J27/049B01D53/8687B01J27/02B01J35/004B01J35/006B01J35/0013B01J35/06C10G45/04B01D2255/20776B01D2255/802B01D2257/70B01J37/0217B01J37/16C02F2305/08C02F2305/10C10G2300/202C10G2300/70C10G2300/703
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Quick Facts
Patent No.
US 9,242,231
App. No.
13/855,258
Granted
Jan 26, 2016
Kind
B2
Abstract

This invention relates to a hybrid component comprising at least one nanoparticle of inorganic layered compound (in the form of fullerene-like structure or nanotube), and at least one metal nanoparticle, uses thereof as a catalyst, (e.g. photocatalysis) and processes for its preparation.

Claims (22)

1. A hybrid comprising at least one inorganic layered compound in the form of fullerene-like structure or a nanotube and at least one metal nanoparticle, wherein said hybrid is a photocatalyst.

2. A hybrid according to claim 1 , wherein said at least one inorganic layered compound is a compound of formula (I):

M p X n   (I)

wherein

M is a metal selected from the group consisting of transition metals, post-transition metals, lanthanoid metals and actinoid metals;

X is selected from the group consisting of S, Se, and Te;

p is 1 or 2; and

n is 1, 2, 3, 4 or 5.

3. A hybrid according to claim 2 , wherein M is selected from W, Mo, V, Zr, Hf, Pt, Re, Nb, Ti, Ga, In, Sn, Pb, Ta and Bi.

4. A hybrid according to claim 1 , wherein said at least one inorganic layered compound is selected from a group consisting of WS 2 , MoS 2 , WSe 2 , MoSe 2 , NbS 2 , ReS 2 , TiS 2 , TaS 2 , ZrS 2 and any combination thereof.

5. A hybrid according to claim 1 , wherein said at least one inorganic layered compound is in the form of a nanotube.

6. A hybrid according to claim 1 , wherein said at least one metal nanoparticle is selected from the group consisting of Ni, Co, Fe, Ti, Cu, V, Mn, Cr, Au, Pt, Pd, Ru, Rh, Ir, Ag, Os and any combination thereof and oxides thereof.

7. A hybrid according to claim 1 , wherein said at least one metal nanoparticle is deposited on the surface of said at least one inorganic layered compound.

8. A hybrid according to claim 1 , wherein said at least one nanoparticle has a particle size of between about 1 mn to about 100 nm.

9. A hybrid according to claim 1 , wherein said inorganic layered compound and nanoparticle have a diameter in the range of between about 20 nm to about 200 nm.

10. A hybrid according to claim 1 , comprising WS 2 nanostructure and at least one metal nanoparticle.

11. A hybrid according to claim 1 , comprising at least one inorganic fullerene-like nanoparticle and at least one metal nanoparticle.

12. A hybrid according to claim 1 , for use as a catalytic agent.

13. A process for the preparation of a hybrid comprising at least one inorganic layered compound or fullerene-like nanoparticle and at least one metal nanoparticle, said process comprising:

providing at least one inorganic layered compound or fullerene-like nanoparticle;

electroless plating at least a portion of the surface of said inorganic layered compound or fullerene-like nanoparticle with at least one metal nanoparticle; thereby providing said hybrid.

14. A method of catalyzing an organic decomposition reaction, comprising performing said organic decomposition reaction in the presence of at least one catalytic agent comprising at least one inorganic layered compound in the form of fullerene-like structure or a nanotube and at least one metal nanoparticle.

Assignments (5)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2014
From: BURGHAUS, UWE; KOMARNENI, MALLIKHARJUNA RAO
To: NORTH DAKOTA STATE UNIVERSITY
Reel/Frame 032986/0680 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2014
From: TENNE, RESHEF; TSVERIN, YULIA
To: YEDA RESEARCH AND DEVELOPMENT CO. LTD.
Reel/Frame 032986/0731 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded May 29, 2014
From: NORTH DAKOTA STATE UNIVERSITY
To: NDSU RESEARCH FOUNDATION
Reel/Frame 032986/0800 →
CONFIRMATORY LICENSE Recorded Dec 6, 2013
From: NORTH DAKOTA STATE UNIVERSITY
To: ENERGY, UNITED STATES DEPARTMENT OF
Reel/Frame 031946/0961 →
CONFIRMATORY LICENSE Recorded Aug 6, 2013
From: NORTH DAKOTA STATE UNIVERSITY
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 030969/0473 →
Continuity (2)
Provisional Application 61619080 · Apr 2, 2012
Related Publication 20140005040A1 · Jan 2, 2014