Composite materials and method for making high-performance carbon nanotube reinforced polymer composites
Nanocomposite materials and methods of making composite materials reinforced with carbon nanotubes are disclosed. The composite material includes an array of functionalized and aligned carbon nanotubes having a degree of functionalization of about 1% to about 10%; and a polymeric matrix material bonded to the array of functionalized and aligned carbon nanotubes.
1. A method for making a composite material comprising:
functionalizing a sheet of carbon nanotubes to produce a sheet of functionalized carbon nanotubes having a degree of functionalization between about 1% to about 10%;
aligning the carbon nanotubes; and, thereafter
impregnating the sheet of functionalized and aligned carbon nanotubes with a matrix material and allowing the sheet of functionalized and aligned carbon nanotubes to bond with the matrix material.
2. The method of claim 1 , wherein the step aligning the carbon nanotubes is performed before functionalizing the sheet of carbon nanotubes.
3. The method of claim 1 , further comprising contacting the sheet of functionalized and aligned carbon nanotubes with a curing agent.
4. The method of claim 3 , wherein the curing agent comprises at least two chemical features selected from the group consisting of an amine, a hydroxyl group, and a double bond.
5. The method of claim 3 , wherein the curing agent comprises DETDA.
6. The method of claim 3 , wherein the curing agent comprises 2-allyl-4-t-butylphenol.
7. The method of claim 1 , wherein the matrix material comprises an epoxide, bismaleimide (BMI), polyimide, canatye, thermoplastic, polyether-ether-ketone (PEEK), polyphenylene sulfide (PPS), polysulfone (PSF), self-reinforcing polymer, polyethersulfone (PES), polycarbonate, or any combination thereof.
8. The method of claim 1 , wherein the matrix material comprises bis(2-(oxiran-2-ylmethoxy)phenyl)methane.
9. The method of claim 1 , wherein the sheet of carbon nanotubes is functionalized by contacting the sheet of carbon nanotubes with a peroxyacid.
10. The method of claim 9 , wherein the peroxyacid is m-CPBA.
11. The method of claim 1 , wherein in the step of aligning the carbon nanotubes, the carbon nanotubes are aligned to an alignment of about 60% or more.
12. The method of claim 11 , wherein in the step of aligning the carbon nanotubes, the carbon nanotubes are aligned to an alignment of about 80% or more.
13. The method of claim 1 , wherein the carbon nanotubes are aligned by stretching the sheet of carbon nanotubes.
14. The method of claim 1 , wherein the degree of functionalization is from about 1% to about 5%.
15. The method of claim 14 , wherein the degree of functionalization is about 4%.