IP Library Granted Patent US 9,476,759
Granted Patent B2
US 9,476,759 · App. 13/864,782 · Granted Oct 25, 2016

Method for determining pore size and pore size distribution of porous material using phase of electro-acoustic signal

Inventors: Andrei S. Dukhin (Goldens Bridge, NY); Matthias Thommes (Royal Palm Beach, FL)
Assignee: Quantachrome Corporation
G01H3/00G01V11/007
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Quick Facts
Patent No.
US 9,476,759
App. No.
13/864,782
Granted
Oct 25, 2016
Kind
B2
Abstract

A method of determining pore size of a porous material. The method includes saturating the porous material with a conducting liquid. Measuring, with an electro-acoustic device, a phase of the seismo-electric or electro-seismic signal at a single frequency or multiple frequencies. Calculating an average pore size from the measured phase of the seismo-electric or electro-seismic signal at single frequency using a theory that takes into account the hydrodynamic relaxation of the conducting liquid inside of the pores of the porous material. Calculating pore size distribution from the similar measurement conducted at multiple frequencies using the same theory.

Claims (10)

1. A method of determining pore size of a porous material comprising:

saturating the porous material with a conducting liquid;

measuring, with an electro-acoustic device, a phase of a seismo-electric or electro-seismic signal within the porous material at a single frequency;

calculating an average pore size from the phase of the seismo-electric or electro-seismic signal using a theory that takes into account a hydrodynamic relaxation of the conducting liquid inside of pores of the porous material, which occurs when d>d cr =√{square root over (πν/4f)}, where d is an average pore diameter of the porous material, ν is a kinematic viscosity of the conducting liquid within the porous material, and f is the frequency of the seismo-electric or electro-seismic signal; and the conducting liquid having an ionic strength sufficient to distinguish the hydrodynamic relaxation from an effect of overlapping double layers.

2. The method according to claim 1 , wherein the frequency equals kinematic viscosity of the conducting liquid divided by a square of an expected pore radius of the porous material.

3. A method of determining pore size distribution of a porous material comprising:

saturating the porous material with a conducting liquid;

measuring, with an electro-acoustic device, a phase of a seismo-electric or electro-seismic signal within the porous material at multiple frequencies;

calculating a pore size distribution from the phase of the seismo-electric or electro-seismic signal using a theory that takes into account a hydrodynamic relaxation of the conducting liquid inside of pores of the porous material, which occurs when d>d cr =√{square root over (πν/4f)}, where d is an average pore diameter of the porous material, ν is a kinematic viscosity of the conducting liquid within the porous material, and f is the frequency of the seismo-electric or electro-seismic signal; and the conducting liquid having an ionic strength sufficient to distinguish the hydrodynamic relaxation from an effect of overlapping double layers.

4. The method according to claim 3 , wherein a frequency range is selected based on the condition that a middle angular frequency of the frequency range equals kinematic viscosity of the conducting liquid divided by a square of an expected pore radius of the porous material.

Assignments (2)
MERGER AND CHANGE OF NAME Recorded Oct 31, 2018
From: ANTON PAAR QUANTATEC INC.; QUANTACHROME CORPORATION
To: ANTON PAAR QUANTATEC, INC.
Reel/Frame 047368/0174 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 22, 2016
From: DUKHIN, ANDREI S.; THOMMES, MATTHIAS
To: QUANTACHROME CORPORATION
Reel/Frame 040107/0349 →
Continuity (2)
Provisional Application 61625456 · Apr 17, 2012
Related Publication 20130269442A1 · Oct 17, 2013