Preparation and application of propargyl ether-containing benzoxazine with high-TG characteristic
The present invention provides benzoxazine containing propargyl group as formula (I): wherein and The present invention provides a method of preparing a compound of formula (I). The present invention also provides a flame resistant resin.
1. A phosphorus based compound represented by formula (I):
wherein
and
2. The compound according to claim 1 , wherein when R 1 and R 2 both are hydrogen atoms in the compound of formula (I), the structural formula of the compound of formula (I) may be:
when R 1 is hydrogen atom and R 2 is —CH 3 in the compound of the aforementioned formula (I), the structural formula of the compound of formula (I) may be:
when R 1 is hydrogen atom and R 2 is
in the compound of the aforementioned formula (I), the structural formula of the compound of formula (I) may be:
when R 1 is
and R 2 is hydrogen atom in the compound of the aforementioned formula (I), the structural formula of the compound of formula (I) may be:
when R 1 is
and R 2 is —CH 3 in the compound of the aforementioned formula (I), the structural formula of the compound of formula (I) may be:
when R 1 is
and R 2 is
in the compound of the aforementioned formula (I), the structural formula of the compound of formula (I) may be: