IP Library Granted Patent US 9,165,762
Granted Patent B2
US 9,165,762 · App. 13/869,369 · Granted Oct 20, 2015

Method of depositing silicone dioxide films

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Quick Facts
Patent No.
US 9,165,762
App. No.
13/869,369
Granted
Oct 20, 2015
Kind
B2
Abstract

A method of forming silicon dioxide films using plasma enhanced chemical vapor deposition (PECVD) uses tetraethyl orthosilicate (TEOS), oxygen or a source of oxygen, and hydrogen as precursors. The method can be carried out at low temperatures in a range of 125 to 175° C. which is useful for manufacturing wafers with through silicon vias.

Claims (10)

1. A method of forming a silicon dioxide film on a substrate, including the steps of:

supplying TEOS via a carrier gas, supplying oxygen or a source of oxygen, and supplying hydrogen as precursors to a chamber containing the substrate, wherein a ratio of a rate of flow of the carrier gas for the TEOS to a rate of flow of hydrogen, to the chamber, is in a range between 0.67:1 and 2:1;

producing a plasma from the precursors; and

performing plasma enhanced chemical vapour deposition using the plasma and while the temperature in the chamber is in a range of 125 to 175° C. to deposit silicon dioxide on the substrate.

2. A method according claim 1 further comprising treating the deposited silicon dioxide with a hydrogen plasma as a post deposition treatment.

3. A method according to claim 2 wherein the hydrogen plasma post deposition treatment is performed after a vacuum break.

4. A method according to claim 2 wherein the hydrogen plasma treatment is carried out at the same temperature as that at which the silicon dioxide is deposited on the substrate by the plasma enhanced chemical vapour deposition.

5. A method according to claim 2 wherein the plasma is produced by exciting the precursors with RF power having a high frequency RF component and a low frequency RF component.

6. A method according to claim 5 wherein the high frequency component is a component having a frequency of 13.56 MHz and power level in a range of 600 to 1200 W and the low frequency component is a component having a frequency of 350 kHz to 2 MHz and power level in a range of from 300 to 500 W.

7. A silicon dioxide film made according to a method as claimed in claim 1 .

Assignments (3)
RELEASE OF SECURITY INTEREST Recorded Jul 5, 2016
From: JPMORGAN CHASE BANK, N.A.
To: SPTS TECHNOLOGIES LIMITED
Reel/Frame 039257/0026 →
SECURITY INTEREST Recorded Apr 2, 2015
From: SPTS TECHNOLOGIES LIMITED
To: JPMORGAN CHASE BANK, N.A., AS ADMINISTRATIVE AGENT
Reel/Frame 035364/0295 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 14, 2013
From: CROOK, KATHRINE; PRICE, ANDREW R; CARRUTHERS, MARK R; ARCHARD, DANIEL R; BURGESS, STEPHEN R
To: SPTS TECHNOLOGIES LIMITED
Reel/Frame 031009/0899 →