IP Library Granted Patent US 9,711,296
Granted Patent B2
US 9,711,296 · App. 13/883,258 · Granted Jul 18, 2017

Energy storage method and system using defect-engineered nanostructures

Inventors: Prabhakar R. Bandaru (San Diego, CA); Mark Hoefer (Malibu, CA)
Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
H01G11/04B82Y30/00B82Y40/00C01B31/0253C01B31/0273H01G9/0029H01G11/24H01G11/30Y02E60/13Y10T29/417
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Quick Facts
Patent No.
US 9,711,296
App. No.
13/883,258
Granted
Jul 18, 2017
Kind
B2
Abstract

An energy storage device includes a first electrode and a second electrode comprising nanostructures. The nanostructures comprise defects that increase charge storage capabilities of the energy storage device. A method of fabricating an energy storage device includes producing a nanomaterial comprising nanostructures and generating defects in the nanomaterial using an electrophilic or nucleophilic additive for increasing charge storage capability of the nanomaterial.

Claims (31)

1. A method of fabricating an energy storage device, the method comprising:

producing a nanomaterial comprising nanostructures;

generating defects, using an electrophilic or nucleophilic additive, in the nanomaterial for increasing charge storage capability of the nanomaterial, further comprising:

depositing the nanomaterial on a first conductive surface of a first electrode;

depositing the nanomaterial on a second conductive surface of a second electrode;

providing a first spacer positioned in close proximity of the first electrode, the first spacer comprising an electron-insulating material;

providing a second spacer positioned in close proximity of the second electrode, the second spacer comprising the electron-insulating material; and

providing a separator positioned between the first spacer and the second spacer, the separator comprising a porous membrane.

2. The method recited in claim 1 , wherein the process of generating defects comprises generating defects using a gaseous additive.

3. The method recited in claim 1 , wherein the process of generating defects comprises generating defects using an organic additive.

4. The method recited in claim 1 , wherein the nanostructures comprise at least one of carbon nanotubes, carbon nanofibers and semiconductor nanowires.

5. The method recited in claim 1 , wherein the nanostructures comprise helical nanotube or nanofibers.

6. A method of operating an energy storage device, the method comprising:

operating an energy storage device having a plurality of electrodes to input an input electrical current and output an output electrical current; and

electrically coupling a defect-engineered nanomaterial to the plurality of electrodes for storing electrical energy, wherein a level of defects is controlled by an additive so that the level of defects in the defect-engineered nanomaterial is a function of a desired input electrical impedance of the energy storage device.

7. The method of claim 6 , wherein the defects comprise electrically charged defects.

8. The method of claim 7 , wherein the electrically charged defects comprise negatively charged defects.

9. The method of claim 6 , wherein the defects comprise electrically neutral defects.

10. The method of claim 6 , wherein the nanostructures comprise carbon nanotubes or carbon nanofibers.

11. The method of claim 6 , wherein the nanostructures comprise semiconductor nanowires.

12. The method of claim 6 , wherein the nanostructures comprise nonlinear nanostructures.

13. A method of controlling input electrical resistance of an energy storage device, the method comprising:

providing the energy storage device with a plurality of electrodes for inputting and outputting electrical current; and

providing a defect-induced nanomaterial, electrically coupled to the plurality of electrodes, for storing electrical energy;

wherein a level of defects in the defect-induced nanomaterial is a function of a desired input electrical impedance of the energy storage device, and wherein the level of defects is controlled by an additive.

14. The method of claim 13 , wherein the defects comprise electrically charged defects.

15. The method of claim 14 , wherein the electrically charged defects comprise negatively charged defects.

16. The method of claim 13 , wherein the defects comprise electrically neutral defects.

17. The method of claim 13 , wherein the nanostructures comprise carbon nanotubes or carbon nanofibers.

18. The method of claim 13 , wherein the nanostructures comprise semiconductor nanowires.

19. The method of claim 13 , wherein the nanostructures comprise nonlinear nanostructures.

Assignments (2)
CONFIRMATORY LICENSE Recorded May 26, 2020
From: UNIVERSITY OF CALIFORNIA, SAN DIEGO
To: NATIONAL SCIENCE FOUNDATION
Reel/Frame 052748/0810 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 14, 2013
From: BANDARU, PRABHAKAR R.; HOEFER, MARK
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 030792/0049 →
Continuity (2)
Provisional Application 61409409 · Nov 2, 2010
Related Publication 20130279076A1 · Oct 24, 2013