Phosphor, light-emitting device and use thereof
The present invention provides: a phosphor which can be combined with a blue LED to emit white light having a low color temperature as in the case where the phosphor is used singly, has a broad fluorescence spectrum, high light emission efficiency, and thermal/chemical stability, and rarely undergoes the deterioration in brightness at higher temperatures. This phosphor is represented by the general formula: Mx(Si,Al)2(N,O)3±y (wherein M independently represent Li or at least one alkali earth metal element; and x and y fulfill the requirement represented by the formulae: 0.52≦x≦0.9 and 0≦y≦0.3) wherein some of M are substituted by element Ce, and wherein the Si/Al atomic ratio is 1.5 to 6 inclusive, the O/N atomic ratio is 0 to 0.1 inclusive, 5-50 mol % of M's is Li, and 0.5-10 mol % of M is Ce.
1. A phosphor represented by formula M x (Si,Al) 2 (N,O) 3±y , provided that M is Li and at least one alkaline earth metal element, 0.52≦x≦0.9, 0.06≦y≦0.23, and part of M is replaced by element Ce, wherein an Si/Al atomic ratio is 1.5 or greater and 6 or less, an o/N atomic ratio is 0 or greater and 0.1 or less, 5 to 50 mol % of M is Li, and 0.5 to 10 mol % of M is Ce, having an orthorhombic crystal structure and comprising a crystal with lattice constant a of 0.935 to 0.965 nm, a lattice constant b of 0.550 to 0.570 nm, and a lattice constant c of 0.480 to 0.500 nm.
2. The phosphor according to claim 1 , wherein 0.5 to 5 mol % of M is Ce.
3. The phosphor according to claim 1 , wherein the alkaline earth metal element is Ca.
4. The phosphor according to claim 1 , consisting of the crystal and a heterogeneous crystal phase, a diffraction intensity of a most intense line of the heterogeneous crystal phase relative to a diffraction intensity of a most intense line of the crystal evaluated by powder X-ray diffractometry being 40% or less.
5. The phosphor according to claim 4 , wherein the heterogeneous crystal phase is α-SiAlON, AlN, or LiSi 2 N 3 .
6. A light-emitting device comprising a phosphor of claim 1 and a light-emitting source.
7. The light-emitting device according to claim 6 , wherein the light-emitting source emits ultraviolet or visible light.
8. An image display device comprising a light-emitting device of claim 6 .
9. A lighting device comprising a light-emitting device of claim 6 .
10. The phosphor according to claim 2 , wherein the alkaline earth metal element is Ca.
11. The phosphor according to claim 2 , having an orthorhombic crystal structure and comprising a crystal with a lattice constant a of 0.935 to 0.965 nm, a lattice constant b of 0.550 to 0.570 nm, and a lattice constant c of 0.480 to 0.500 nm.
12. The phosphor according to claim 3 , having an orthorhombic crystal structure and comprising a crystal with a lattice constant a of 0.935 to 0.965 nm, a lattice constant b of 0.550 to 0.570 nm, and a lattice constant c of 0.480 to 0.500 nm.
13. A light-emitting device comprising a phosphor of claim 2 and a light-emitting source.
14. A light-emitting device comprising a phosphor of claim 3 and a light-emitting source.
15. A light-emitting device comprising a phosphor of claim 4 and a light-emitting source.
16. A light-emitting device comprising a phosphor of claim 5 and a light-emitting source.
17. An image display device comprising a light-emitting device of claim 7 .
18. A lighting device comprising a light-emitting device of claim 7 .