Temperature Control Method in a Laboratory Scale Reactor
Disclosed herein is a method of separating variations in the mass flow of gas through a catalyst from the thermal load observed by the temperature control system in a test bench. The method may include separating the temperature control component from the mass flow control component.
1 . An apparatus for analyzing a fluid, comprising:
a heating chamber comprising at least one heating element suitable for heating the fluid to a heating temperature and for imparting a first space velocity to the fluid;
a heating controller suitable for controlling the heating temperature of the fluid;
at least one catalyst sample provided substantially in-line following the heating chamber and suitable for interacting with a first portion of the fluid having a second space velocity;
at least one vent suitable for venting, prior to interacting with the catalyst sample, of a second portion of the fluid, thereby imparting the second space velocity to the first portion of the fluid;
at least one mass flow controller for controlling flow of a mass-flow controlled one of the interacted first portion of the fluid; and
at least three outputs, comprising:
a first output suitable for outputting the mass flow controlled one of the interacted first portion;
a second output suitable for substantially directly outputting a pre-treated one of the interacted first portion; and
a third output suitable for substantially directly outputting the interacted first portion.
2 . The apparatus of claim 1 , further comprising a calayst holder suitable for receiving the interacted first portion substantially directly from the catalyst sample.
3 . The apparatus of claim 1 , wherein the first space velocity is not equal to the second space velocity.
4 . The apparatus of claim 1 , wherein the at least one fluid comprises gas.
5 . The apparatus of claim 1 , wherein the heating controller controls a rate of the heating.
6 . The apparatus of claim 1 , wherein the heating controller comprises one selected from the group consisting of a thermocouple, thermistor, and any combination thereof.
7 . The apparatus of claim 1 , wherein the heating element comprises a serpentine heater.
8 . The appartus of claim 1 , further comprising a pre-treatment device suitable for providing the pre-treated one of the interacted first portion.
9 . The apparatus of claim 8 , wherein the pre-treatment device comprises one selected from the group consisting of a heat block, cooling bath, and combinations thereof.
10 . The apparatus of claim 1 , further comprising at least one analyzer suitable for analyzing the fluid output at at least one of the at least three outputs.
11 . The apparatus of claim 10 , wherein the analyzing comprises one selected from the group consisting of flame ionization detection, CO detection, hydrocarbon detection, fourier transform infrared detection, and combinations thereof.
12 . A method for analyzing at least one fluid, comprising:
heating at least one fluid in a heating chamber, the heating chamber comprising at least one heating element and at least one heating control for controlling a heating temperature of the at least one fluid;
venting at least a second portion of the at least one fluid after said heating;
interacting a first, non-vented portion of the at least one fluid with a catalyst after said venting;
controlling a flow of the interacted first, non-vented portion of the at least one fluid utilizing at least one mass flow controller;
outputting at least a flow contolled one of the interacted first, non-vented portion of the at least one fluid, and a non-flow controlled one of the interacted first, non-vented portion of the at least one fluid.
13 . The method of claim 12 , wherein, prior to said venting, the at least one fluid comprises a first space velocity, and wherein, following said venting, the at least one fluid comprises a second space velocity, and wherein the first space velocity is unequal to the second space velocity.
14 . The apparatus of claim 12 , wherein the at least one fluid comprises gas.
15 . The method of claim 12 , further comprising controlling a rate of the heating via the heating control.
16 . The method of claim 12 , wherein the heating element comprises a serpentine heater.
17 . The method of claim 12 , further comprising pre-treating the interacted first, non-vented portion using a pre-treatment device.
18 . The method of claim 17 , wherein the pre-treatment device comprises one selected from the group consisting of a heat block, cooling bath, and combinations thereof.
19 . The method of claim 12 , further comprising analyzing at least one of the outputted interacted first, non-vented portions of the at least one fluid.
20 . The method of claim 19 , wherein the analyzing comprises one selected from the group consisting of flame ionization detection, CO detection, hydrocarbon detection, fourier transform infrared detection, and combinations thereof.