IP Library › Granted Patent US 9,203,043
Granted Patent B2
US 9,203,043 · App. 13/902,355 · Granted Dec 1, 2015

Organic electroluminescence device

Inventors: Kazuki Nishimura (Sodegaura, JP); Tetsuya Inoue (Sodegaura, JP); Yumiko Mizuki (Sodegaura, JP); Nobuhiro Yabunouchi (Sodegaura, JP); Mitsuru Eida (Sodegaura, JP)
Assignee: IDEMITSU KOSAN CO., LTD.
H01L51/5012C09K11/06H01L51/0072H01L51/5024C09K2211/185H01L51/0067H01L51/0085H01L51/504H01L51/5016H01L51/5044H01L2251/308H01L2251/5376H01L2251/5384
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Quick Facts
Patent No.
US 9,203,043
App. No.
13/902,355
Granted
Dec 1, 2015
Kind
B2
Abstract

An organic electroluminescence device 1 includes: an anode 3 , a cathode 4 opposed to the anode 3 and an emitting layer 5 provided between the anode 3 and the cathode 4 . The emitting layer 5 contains first and second host materials and a luminescent material. The first host material has a partial structure represented by at least one of the following formulae (1) and (2) while the second host material has a partial structure represented by the following formula (3). Az represents a substituted or unsubstituted aromatic heterocyclic group containing a nitrogen-containing six-membered ring. W CN is an aromatic hydrocarbon group substituted by at least one cyano group (CN) or an aromatic heterocyclic group substituted by at least one cyano group (CN). Ar 1 is a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group, but is not an aromatic heterocyclic group containing a nitrogen-containing six-membered ring. —Az—(W CN ) p   (1) —Az—(CN) q   (2) —Ar 1 —(CN) r   (3)

Claims (169)

1. An organic electroluminescence device comprising:

an anode;

a cathode opposed to the anode; and

an emitting layer provided between the anode and the cathode, wherein

the emitting layer comprises a first host material, a second host material and a luminescent material,

the first host material comprises a partial structure represented by at least one of the following formulae (1) and (2), and

the second host material comprises a partial structure represented by the following formula (3) and does not comprise a partial structure represented by the formula (1) or the formula (2),

-Az-(W CN ) p   (1)

-Az-(CN) q   (2)

—Ar 1 —(CN) r   (3)

where: in the formula (1),

Az represents a substituted or unsubstituted aromatic heterocyclic group comprising a nitrogen-containing six-membered ring,

W CN is an aromatic hydrocarbon group substituted by at least one cyano group (CN) or an aromatic heterocyclic group substituted by at least one cyano group (CN),

p is an integer of 1 or more, and

W CN optionally comprises a substituent other than the cyano group and, when a plurality of W CN are present, the plurality of W CN are mutually the same or different;

In the formula (2),

Az represents the same as Az of the formula (1), and

q is an integer of 1 or more; and

in the formula (3),

Ar 1 is a substituted or unsubstituted aromatic hydrocarbon group or a substituted or unsubstituted aromatic heterocyclic group, but is not an aromatic heterocyclic group comprising a nitrogen-containing six-membered ring, and

r is an integer of 1 or more.

2. The organic electroluminescence device according to claim 1 , wherein

the first host material is represented by at least one of the formulae (1-1) and (2-1), and

the second host material is represented by the following formula (3-1),

Ar 2 -Az-(W CN ) p   (1-1)

Ar 2 -Az-(CN) q   (2-1)

Ar 3 —Ar 1 —(CN) r   (3-1)

where:

Ar 2 and Ar 3 each independently represent a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms,

Az, W CN and p in the formula (1-1) are the same as Az, W CN and p in the formula (1),

Az and q in the formula (2-1) are the same as Az and q in the formula (2), and

Ar 1 and r in the formula (3-1) are the same as Ar 1 and r in the formula (3).

3. The organic electroluminescence device according to claim 1 , wherein

the first host material is represented by the following formula (4),

where:

M 1 represents a group represented by one of the formulae (1) and (2),

L 1 represents a single bond, a substituted or unsubstituted polyvalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted polyvalent aromatic heterocyclic group having 5 to 30 ring atoms, a cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the polyvalent aromatic hydrocarbon group, the polyvalent aromatic heterocyclic group and the cycloalkylene group,

k is 1 or 2,

X 11 to X 18 each independently represent a nitrogen atom or CR b ,

R b each independently represents a hydrogen atom, a halogen atom, a cyano group, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 30 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 30 ring carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 ring carbon atoms, and a substituted or unsubstituted aryloxy group having 6 to 30 ring carbon atoms, and

a part of one of adjacent two R b in X 11 to X 18 is optionally bonded to a part of the other R b to form a cyclic structure.

4. The organic electroluminescence device according to claim 1 , wherein

the second host material is represented by the following formula (5),

where:

A 1 represents a group represented by the formula (3),

X 1 to X 8 each independently represent N (nitrogen atom) or CR a ,

R a each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, a halogen atom, or a cyano group, when a plurality of R a are present, the plurality of R a are the same or different, and

when at least adjacent two of X 1 to X 4 and X 5 to X 8 are CR a , a part of R a in the adjacent CR a is optionally bonded to a part of the other R a to form a cyclic structure.

5. The organic electroluminescence device according to claim 3 , wherein

the first host material is represented by at least one of the following formulae (4-3) and (4-4),

where:

L 1 and X 11 to X 18 are the same as L 1 and X 11 to X 18 in the formula (4),

Az, W CN and p in the formula (4-3) are the same as Az, W CN and p in the formula (1), and

Az and q in the formula (4-4) are the same as Az and q in the formula (1).

6. The organic electroluminescence device according to claim 4 , wherein

the first host material is represented by at least one of the following formulae (4-3) and (4-4),

where:

L 1 represents a single bond, a substituted or unsubstituted polyvalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted polyvalent aromatic heterocyclic group having 5 to 30 ring atoms, a cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the polyvalent aromatic hydrocarbon group, the polyvalent aromatic heterocyclic group and the cycloalkylene group,

X 11 to X 18 each independently represent a nitrogen atom or CR b ,

R b each independently represents a hydrogen atom, a halogen atom, a cyano group, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 30 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 30 ring carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 ring carbon atoms, and a substituted or unsubstituted aryloxy group having 6 to 30 ring carbon atoms, and

a part of one of adjacent two R b in X 11 to X 18 is optionally bonded to a part of the other R b to form a cyclic structure,

Az, W CN and p in the formula (4-3) are the same as Az, W CN and p in the formula (1), and

Az and q in the formula (4-4) are the same as Az and q in the formula (1).

7. The organic electroluminescence device according to claim 1 , wherein

the second host material is represented by the following formula (5-1),

where:

A 1 represents the group having the partial structure represented by the formula (3),

A 2 each independently represents the group having the partial structure represented by the formula (3), a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms,

A 3 represents a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the divalent aromatic hydrocarbon group, the divalent aromatic heterocyclic group and the cycloalkylene group,

m is an integer of 0 to 3,

X 1 to X 4 and Y 5 to Y 8 each independently represent N (nitrogen atom) or CR a ,

X 5 to X 8 and Y 1 to Y 4 each independently represent N (nitrogen atom), CR a or a carbon atom to be bonded to A 3 ,

R a in X 1 to X 8 and Y 1 to Y 8 each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, a halogen atom, or a cyano group,

when a plurality of R a are present, the plurality of R a are the same or different, and

when at least adjacent two of X 1 to X 8 and Y 1 to Y 8 are CR a , a part of R a in the adjacent CR a is optionally bonded to a part of the other R a to form a cyclic structure.

8. The organic electroluminescence device according to claim 3 , wherein

the second host material is represented by the following formula (5-1),

where:

A 1 represents the group having the partial structure represented by the formula (3),

A 2 each independently represents the group having the partial structure represented by the formula (3), a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms,

A 3 represents a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the divalent aromatic hydrocarbon group, the divalent aromatic heterocyclic group and the cycloalkylene group,

m is an integer of 0 to 3,

X 1 to X 4 and Y 5 to Y 8 each independently represent N (nitrogen atom) or CR a ,

X 5 to X 8 and Y 1 to Y 4 each independently represent N (nitrogen atom), CR a or a carbon atom to be bonded to A 3 ,

R a in X 1 to X 8 and Y 1 to Y 8 each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, a halogen atom, or a cyano group,

when a plurality of R a are present, the plurality of R a are the same or different, and

when at least adjacent two of X 1 to X 8 and Y 1 to Y 8 are CR a , a part of R a in the adjacent CR a is optionally bonded to a part of the other R a to form a cyclic structure.

9. The organic electroluminescence device according to claim 5 , wherein

the second host material is represented by the following formula (5-1),

where:

A 1 represents the group having the partial structure represented by the formula (3),

A 2 each independently represents the group having the partial structure represented by the formula (3), a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms,

A 3 represents a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the divalent aromatic hydrocarbon group, the divalent aromatic heterocyclic group and the cycloalkylene group,

m is an integer of 0 to 3,

X 1 to X 4 and Y 5 to Y 8 each independently represent N (nitrogen atom) or CR a ,

X 5 to X 8 and Y 1 to Y 4 each independently represent N (nitrogen atom), CR a or a carbon atom to be bonded to A 3 ,

R a in X 1 to X 8 and Y 1 to Y 8 each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, a halogen atom, or a cyano group,

when a plurality of R a are present, the plurality of R a are the same or different, and

when at least adjacent two of X 1 to X 8 and Y 1 to Y 8 are CR a , a part of R a in the adjacent CR a is optionally bonded to a part of the other R a to form a cyclic structure.

10. The organic electroluminescence device according to claim 3 , wherein

the first host material is represented by the following formula (4-5),

where:

L 1 represents the same as L 1 in the formula (4),

X 11 to X 14 and X 45 to X 48 each independently represent a nitrogen atom or CR b ,

X 15 to X 18 and X 41 to X 44 each independently represent a nitrogen atom, CR b or a carbon atom to be bonded to L 2 ,

R b of CR b in X 11 to X 18 and X 41 to X 48 is the same as R b of CR b in X 11 to X 18 in the formula (4),

L 2 and L 3 each independently represent a single bond, a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent aromatic heterocyclic group having 5 to 30 ring atoms, a cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the divalent aromatic hydrocarbon group, the divalent aromatic heterocyclic group and the cycloalkylene group,

a part of one of at least adjacent two R b in X 11 to X 18 and X 41 to X 48 is optionally bonded to a part of the other R b to form a cyclic structure,

M 1 represents a group represented by one of the formulae (1) and (2),

M 2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, or a group represented by one of the formulae (1) and (2), and

M 1 and M 2 are the same or different.

11. The organic electroluminescence device according to claim 7 , wherein

the first host material is represented by the following formula (4-5),

where:

L 1 represents a single bond, a substituted or unsubstituted polyvalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted polyvalent aromatic heterocyclic group having 5 to 30 ring atoms, a cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the polyvalent aromatic hydrocarbon group, the polyvalent aromatic heterocyclic group and the cycloalkylene group,

X 11 to X 14 and X 45 to X 48 each independently represent a nitrogen atom or CR b ,

X 15 to X 18 and X 41 to X 44 each independently represent a nitrogen atom, CR b or a carbon atom to be bonded to L 2 ,

R b of CR b in X 11 to X 18 and X 41 to X 48 each independently represents a hydrogen atom, a halogen atom, a cyano group, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted alkenyl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkynyl group having 2 to 30 carbon atoms, a substituted or unsubstituted alkylsilyl group having 3 to 30 carbon atoms, a substituted or unsubstituted arylsilyl group having 6 to 30 ring carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 30 carbon atoms, a substituted or unsubstituted aralkyl group having 6 to 30 ring carbon atoms, and a substituted or unsubstituted aryloxy group having 6 to 30 ring carbon atoms,

L 2 and L 3 each independently represent a single bond, a substituted or unsubstituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted divalent aromatic heterocyclic group having 5 to 30 ring atoms, a cycloalkylene group having 5 to 30 ring carbon atoms, or a group provided by linking the divalent aromatic hydrocarbon group, the divalent aromatic heterocyclic group and the cycloalkylene group,

a part of one of at least adjacent two R b in X 11 to X 18 and X 41 to X 48 is optionally bonded to a part of the other R b to form a cyclic structure,

M 1 represents a group represented by one of the formulae (1) and (2),

M 2 represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, or a group represented by one of the formulae (1) and (2), and

M 1 and M 2 are the same or different.

12. The organic electroluminescence device according to claim 1 , wherein

Az is a divalent to pentavalent group of a ring represented by the following formula (4-6),

where:

Y 11 to Y 15 each independently represent a nitrogen atom (N) or CR c ,

R c of CR c each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, or a halogen atom,

when adjacent two of Y 11 to Y 15 are CR c , a part of R c of the adjacent CR c is optionally bonded to a part of the other R c to form a cyclic structure,

when a plurality of R c are present, the plurality of R c are mutually the same or different.

13. The organic electroluminescence device according to claim 3 , wherein

Az is a divalent to pentavalent group of a ring represented by the following formula (4-6),

where:

Y 11 to Y 15 each independently represent a nitrogen atom (N) or CR c ,

R c of CR c each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, or a halogen atom,

when adjacent two of Y 11 to Y 15 are CR c , a part of R c of the adjacent CR c is optionally bonded to a part of the other R c to form a cyclic structure, and

when a plurality of R c are present, the plurality of R c are mutually the same or different.

14. The organic electroluminescence device according to claim 5 , wherein

Az a divalent to pentavalent group of a ring represented by the following formula (4-6),

where:

Y 11 to Y 15 each independently represent a nitrogen atom (N) or CR c ,

R c of CR c each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, or a halogen atom,

when adjacent two of Y 11 to Y 15 are CR c , a part of R c of the adjacent CR c is optionally bonded to a part of the other R c to form a cyclic structure, and

when a plurality of R c are present, the plurality of R c are mutually the same or different.

15. The organic electroluminescence device according to claim 10 , wherein

Az a divalent to pentavalent group of a ring represented by the following formula (4-6),

where:

Y 11 to Y 15 each independently represent a nitrogen atom (N) or CR c ,

R c of CR c each independently represents a hydrogen atom, a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, a substituted or unsubstituted aromatic heterocyclic group having 5 to 30 ring atoms, a substituted or unsubstituted alkyl group having 1 to 30 carbon atoms, a substituted or unsubstituted silyl group, or a halogen atom,

when adjacent two of Y 11 to Y 15 are CR c , a part of R c of the adjacent CR c is optionally bonded to a part of the other R c to form a cyclic structure, and

when a plurality of R c are present, the plurality of R c are mutually the same or different.

16. The organic electroluminescence device according to claim 10 , wherein

the first host material represented by the formula (4-5) is represented by one of the following formulae (4-5-1), (4-5-2) and (4-5-3),

where: M 1 , M 2 , L 1 , L 2 , L 3 , X 11 to X 18 , and X 41 to X 48 represent the same as M 1 , M 2 , L 1 , L 2 , L 3 , X 11 to X 18 , and X 41 to X 48 in the formula (4-5).

17. The organic electroluminescence device according to claim 7 , wherein

the second host material represented by the formula (5-1) is preferably represented by one of the following formulae (5-1-1), (5-1-2) and (5-1-3),

where:

in the formula (5-1-1),

A 1 , A 2 , A 3 , X 1 to X 5 , X 7 , X 8 , Y 1 , Y 2 , Y 4 to Y 8 and m represent the same as A 1 , A 2 , A 3 , X 1 to X 5 , X 7 , X 8 , Y 1 , Y 2 , Y 4 to Y 8 and m in the formula (5-1), and X 6 and Y 3 are carbon atoms,

in the formula (5-1-2),

A 1 , A 2 , A 3 , X 1 to X 5 , X 7 , X 8 , Y 1 , Y 3 to Y 8 and m represent the same as A 1 , A 2 , A 3 , X 1 to X 5 , X 7 , X 8 , Y 1 , Y 3 to Y 8 and m in the formula (5-1), and X 6 and Y 2 are carbon atoms, and

in the formula (5-1-3),

A 1 , A 2 , A 3 , X 1 to X 6 , X 8 , Y 1 , Y 2 , Y 4 to Y 8 and m represent the same as A 1 , A 2 , A 3 , X 1 to X 6 , X 8 , Y 1 , Y 2 , Y 4 to Y 8 and m in the formula (5-1), and X 7 and Y 3 are carbon atoms.

18. The organic electroluminescence device according to claim 1 , wherein

at least one of the partial structures represented by the formula (3) of the second host material is a cyano-substituted phenyl group, a cyano-substituted naphthyl group, a cyano-substituted phenanthryl group, a cyano-substituted dibenzofuranyl group, a cyano-substituted biphenylyl group, a cyano-substituted terphenylyl group, or a cyano-substituted triphenylenyl group.

19. The organic electroluminescence device according to claim 1 , wherein

the luminescent material comprises a phosphorescent material that is an ortho-metalated complex of a metal atom selected from iridium (Ir), osmium (Os) and platinum (Pt).

20. The organic electroluminescence device according to claim 19 , wherein

a wavelength of an emission peak of the phosphorescent material is 490 nm to 700 nm.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Jul 26, 2013
From: NISHIMURA, KAZUKI; INOUE, TETSUYA; MIZUKI, YUMIKO; YABUNOUCHI, NOBUHIRO; EIDA, MITSURU
To: IDEMITSU KOSAN CO., LTD.
Reel/Frame 030883/0890 →
Priority Claims (1)
JP 2012-121401 · May 28, 2012 · national
Continuity (2)
Provisional Application 61657313 · Jun 8, 2012
Related Publication 20130313536A1 · Nov 28, 2013